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Ferroelectricity coexisted with p-orbital ferromagnetism and metallicity in two-dimensional metal oxynitrides
Haoqiang Ai1; Feifei Li2; Haoyun Bai2; Dong Liu2; Kin Ho Lo1; Shengyuan A. Yang3,4; Yoshiyuki Kawazoe5,6,7; Hui Pan2,8
2022-04-08
Source Publicationnpj Computational Materials
ISSN2057-3960
Volume8Issue:1Pages:60
Other Abstract

Two-dimensional (2D) multiferroics have attracted increasing interests in basic science and technological fields in recent years. However, most reported 2D magnetic ferroelectrics are based on the d-electron magnetism, which makes them rather rare due to the empirical d rule and limits their applications for low magnetic phase transition temperature. In this work, we demonstrate that the ferroelectricity can coexist with the p-electron-induced ferromagnetism without the limitation of d rule and metallicity in a family of stable 2D MXene-analogous oxynitrides, XNO (X = In, Tl). Remarkably, the itinerant character of p electrons can lead to the strong ferromagnetic metallic states. Furthermore, a possible magnetoelectric effect is manifested in a TlNO/WTe heterostructure through the interface engineering. Our findings provide an alternative possible route toward 2D multiferroics and enrich the concept of ferroelectric metals.

DOI10.1038/s41524-022-00737-3
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Materials Science
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary
WOS IDWOS:000780310100002
PublisherNATURE PORTFOLIO, HEIDELBERGER PLATZ 3, BERLIN 14197, GERMANY
Scopus ID2-s2.0-85127942237
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionFaculty of Science and Technology
INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
DEPARTMENT OF ELECTROMECHANICAL ENGINEERING
DEPARTMENT OF PHYSICS AND CHEMISTRY
Corresponding AuthorKin Ho Lo; Hui Pan
Affiliation1.Department of Electromechanical Engineering, Faculty of Science and Technology, University of Macau, Taipa, SAR, 999078, Macao
2.Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, SAR, 999078, Macao
3.Research Laboratory for Quantum Materials, Singapore University of Technology and Design, Singapore, 487372, Singapore
4.Center for Quantum Transport and Thermal Energy Science, School of Physics and Technology, Nanjing Normal University, Nanjing, 210023, China
5.New Industry Creation Hatchery Center, Tohoku University, Sendai, 980-8579, Japan
6.Department of Physics and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu, 603203, India
7.School of Physics, Suranaree University of Technology, Nakhon Ratchasima, 111 University Avenue Muang, 30000, Thailand
8.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, Taipa, SAR, 999078, Macao
First Author AffilicationFaculty of Science and Technology
Corresponding Author AffilicationFaculty of Science and Technology;  INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Haoqiang Ai,Feifei Li,Haoyun Bai,et al. Ferroelectricity coexisted with p-orbital ferromagnetism and metallicity in two-dimensional metal oxynitrides[J]. npj Computational Materials, 2022, 8(1), 60.
APA Haoqiang Ai., Feifei Li., Haoyun Bai., Dong Liu., Kin Ho Lo., Shengyuan A. Yang., Yoshiyuki Kawazoe., & Hui Pan (2022). Ferroelectricity coexisted with p-orbital ferromagnetism and metallicity in two-dimensional metal oxynitrides. npj Computational Materials, 8(1), 60.
MLA Haoqiang Ai,et al."Ferroelectricity coexisted with p-orbital ferromagnetism and metallicity in two-dimensional metal oxynitrides".npj Computational Materials 8.1(2022):60.
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