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Multi-Component Crosslinked Hydrogel Electrolyte toward Dendrite-Free Aqueous Zn Ion Batteries with High Temperature Adaptability
Lu, Hongyu1,2; Hu, Jisong3; Wang, Litong4; Li, Jianzhu1,2; Ma, Xiang2; Zhu, Zhicheng2; Li, Heqi2; Zhao, Yingjie2; Li, Yujie1,2; Zhao, Jingxin5; Xu, Bingang5
2022-01-27
Source PublicationAdvanced Functional Materials
ISSN1616-301X
Volume32Issue:19Pages:2112540
Abstract

Rechargeable aqueous Zn-ion batteries (ZIBs) are always regarded as a promising energy storage device owing to their higher safety and durability. However, two problems have become the main trouble for the practical application of ZIBs such as the dendrite growth of Zn metal anode in electrolyte and the freezing of water solvent at low temperature. Herein, to overcome these challenges, a new strategy, multi-component crosslinked hydrogel electrolyte, is proposed to inhibit Zn dendrites and realize low temperature environmental adaptability for ZIBs. Benefitting from the superior inhibition effect of the polyacrylamide and dimethyl sulfoxide (DMSO) on Zn dendrites, the coulombic efficiency of the symmetric cell of ≈99.5% is achieved during the Zn plating/stripping over 1 300 h, and the assembled full-cell demonstrates the large specific capacity of 265.2 mAh g-1 and high cyclic stability with the capacity retention of 95.27% after 3 000 cycles. In addition, the full-cell delivers stable operation at a wide temperature range, from 60 to −40 °C, due to the introduction of additive DMSO. This work provides an inspired strategy and novel opportunities to realize a dendrite-free and wide-temperature rechargeable aqueous Zn-ion energy storage system.

KeywordAqueous Zn Ion Batteries Highly Reversible Zn Anodes Hydrogel Electrolytes Wide-temperature Range Zn Dendrites
DOI10.1002/adfm.202112540
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000747600900001
PublisherWILEY-V C H VERLAG GMBH
Scopus ID2-s2.0-85123789472
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorLi, Yujie; Zhao, Jingxin; Xu, Bingang
Affiliation1.State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, China
2.School of Materials Science and Engineering, Harbin Institute of Technology (Weihai), Weihai, 264209, China
3.School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, 430074, China
4.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, SAR, 999078, Macao
5.Nanotechnology Center, Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Kowloon, Hung Hom, 999077, Hong Kong
Recommended Citation
GB/T 7714
Lu, Hongyu,Hu, Jisong,Wang, Litong,et al. Multi-Component Crosslinked Hydrogel Electrolyte toward Dendrite-Free Aqueous Zn Ion Batteries with High Temperature Adaptability[J]. Advanced Functional Materials, 2022, 32(19), 2112540.
APA Lu, Hongyu., Hu, Jisong., Wang, Litong., Li, Jianzhu., Ma, Xiang., Zhu, Zhicheng., Li, Heqi., Zhao, Yingjie., Li, Yujie., Zhao, Jingxin., & Xu, Bingang (2022). Multi-Component Crosslinked Hydrogel Electrolyte toward Dendrite-Free Aqueous Zn Ion Batteries with High Temperature Adaptability. Advanced Functional Materials, 32(19), 2112540.
MLA Lu, Hongyu,et al."Multi-Component Crosslinked Hydrogel Electrolyte toward Dendrite-Free Aqueous Zn Ion Batteries with High Temperature Adaptability".Advanced Functional Materials 32.19(2022):2112540.
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