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Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery
Li, Junfeng1; Hui, Kwan San2; Ji, Shunping1; Zha, Chenyang1; Yuan, Chengzong1; Wu, Shuxing3; Bin, Feng4; Fan, Xi5; Chen, Fuming6; Shao, Zongping7,8; Hui, Kwun Nam1
2022-03-01
Source PublicationCarbon Energy
Volume4Issue:2Pages:155-169
Abstract

Aluminum–metal batteries show great potential as next-generation energy storage due to their abundant resources and intrinsic safety. However, the crucial limitations of metallic Al anodes, such as dendrite and corrosion problems in conventional aluminum–metal batteries, remain challenging and elusive. Here, we report a novel electrodeposition strategy to prepare an optimized 3D Al anode on carbon cloth with an uniform deposition morphology, low local current density, and mitigatory volume change. The symmetrical cells with the 3D Al anode show superior stable cycling (>450 h) and low-voltage hysteresis (~170 mV) at 0.5 mA cm. High reversibility (~99.7%) is achieved for the Al plating/stripping. The graphite | | Al-4/CC full batteries show a long lifespan of 800 cycles with 54 mAh g capacity at a high current density of 1000 mA g, benefiting from the high capacitive-controlled distribution. This study proposes a novel strategy to design 3D Al anodes for metallic-Al-based batteries by eliminating the problems of planar Al anodes and realizing the potential applications of aluminum–graphite batteries.

Keyword3d Al Anode Ionic Liquid Metallic Plating/stripping Stability
DOI10.1002/cey2.155
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Energy & Fuels ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Physical ; Energy & Fuels ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000713345500001
Scopus ID2-s2.0-85118308173
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorHui, Kwan San; Shao, Zongping; Hui, Kwun Nam
Affiliation1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, China
2.School of Engineering, Faculty of Science, University of East Anglia, Norwich, United Kingdom
3.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, China
4.State Key Laboratory of High-Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing, China
5.Ningbo Institute of Materials Technology, Engineering, Chinese Academy of Sciences, Ningbo, China
6.Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou, China
7.State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, China
8.WA School of Mines: Minerals, Energy and Chemical Engineering (WASM-MECE), Curtin University, Perth, Australia
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Li, Junfeng,Hui, Kwan San,Ji, Shunping,et al. Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery[J]. Carbon Energy, 2022, 4(2), 155-169.
APA Li, Junfeng., Hui, Kwan San., Ji, Shunping., Zha, Chenyang., Yuan, Chengzong., Wu, Shuxing., Bin, Feng., Fan, Xi., Chen, Fuming., Shao, Zongping., & Hui, Kwun Nam (2022). Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery. Carbon Energy, 4(2), 155-169.
MLA Li, Junfeng,et al."Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery".Carbon Energy 4.2(2022):155-169.
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