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Status | 已發表Published |
Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery | |
Li, Junfeng1; Hui, Kwan San2![]() ![]() ![]() ![]() | |
2022-03-01 | |
Source Publication | Carbon Energy
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Volume | 4Issue:2Pages:155-169 |
Abstract | Aluminum–metal batteries show great potential as next-generation energy storage due to their abundant resources and intrinsic safety. However, the crucial limitations of metallic Al anodes, such as dendrite and corrosion problems in conventional aluminum–metal batteries, remain challenging and elusive. Here, we report a novel electrodeposition strategy to prepare an optimized 3D Al anode on carbon cloth with an uniform deposition morphology, low local current density, and mitigatory volume change. The symmetrical cells with the 3D Al anode show superior stable cycling (>450 h) and low-voltage hysteresis (~170 mV) at 0.5 mA cm. High reversibility (~99.7%) is achieved for the Al plating/stripping. The graphite | | Al-4/CC full batteries show a long lifespan of 800 cycles with 54 mAh g capacity at a high current density of 1000 mA g, benefiting from the high capacitive-controlled distribution. This study proposes a novel strategy to design 3D Al anodes for metallic-Al-based batteries by eliminating the problems of planar Al anodes and realizing the potential applications of aluminum–graphite batteries. |
Keyword | 3d Al Anode Ionic Liquid Metallic Plating/stripping Stability |
DOI | 10.1002/cey2.155 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Energy & Fuels ; Science & Technology - Other Topics ; Materials Science |
WOS Subject | Chemistry, Physical ; Energy & Fuels ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:000713345500001 |
Scopus ID | 2-s2.0-85118308173 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Hui, Kwan San; Shao, Zongping; Hui, Kwun Nam |
Affiliation | 1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, China 2.School of Engineering, Faculty of Science, University of East Anglia, Norwich, United Kingdom 3.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, China 4.State Key Laboratory of High-Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing, China 5.Ningbo Institute of Materials Technology, Engineering, Chinese Academy of Sciences, Ningbo, China 6.Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou, China 7.State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, China 8.WA School of Mines: Minerals, Energy and Chemical Engineering (WASM-MECE), Curtin University, Perth, Australia |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Li, Junfeng,Hui, Kwan San,Ji, Shunping,et al. Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery[J]. Carbon Energy, 2022, 4(2), 155-169. |
APA | Li, Junfeng., Hui, Kwan San., Ji, Shunping., Zha, Chenyang., Yuan, Chengzong., Wu, Shuxing., Bin, Feng., Fan, Xi., Chen, Fuming., Shao, Zongping., & Hui, Kwun Nam (2022). Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery. Carbon Energy, 4(2), 155-169. |
MLA | Li, Junfeng,et al."Electrodeposition of a dendrite-free 3D Al anode for improving cycling of an aluminum–graphite battery".Carbon Energy 4.2(2022):155-169. |
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