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Roadmap on the protective strategies of zinc anodes in aqueous electrolyte
Li, Chaowei1,2; Wang, Litong2; Zhang, Jingchao1; Zhang, Daojun1; Du, Jimin1; Yao, Yagang4,5; Hong, Guo2,3
Source PublicationEnergy Storage Materials
ISSN2405-8297
2022-01
Abstract

Rechargeable aqueous zinc (Zn) batteries have captured extensive attentions as auspicious next generation energy storage devices due to the merits of low cost, high capacity, inherent safety, and abundant resources. However, the humble poor durability and low coulombic efficiency of Zn anodes seriously hinder their wide applications. Zn batteries can be classified into two classifications: alkaline and neutral Zn batteries, according to the nature of electrolyte. Due to the different electrochemical behaviors of Zn anodes in the alkaline and neutral electrolytes, the fundamental comprehensions of Zn anodes in both electrolytes remain dubious. In this review, the fundamental reactions of Zn anodes in alkaline and neutral electrolytes were elucidated in detail. Specifically, the primary reasons (including surface passivation, dendritic growth, hydrogen evolution, and shape change in the Zn stripping/plating procedure) which lead to the pitiable durability and low coulombic efficiency of Zn anodes in both electrolytes were profoundly illuminated, respectively. Moreover, the most recent progresses about the Zn anodes protective strategies to settle the above critical problems were systematically recapitulated and clarified, including the surface modification, structural and constitution design, electrolyte modification and other protective strategies. Finally, the challenges and opportunities in high-performance Zn anodes are further expected. This review will shed light on the exploit of advanced Zn anodes for high-performance Zn batteries in both alkaline and neutral electrolytes.

KeywordHydrogen Evolution Protective Strategies Zn Anodes Zn Dendrite Zn Electrochemistry
Language英語English
DOI10.1016/j.ensm.2021.10.020
URLView the original
Volume44
Pages104-135
WOS IDWOS:000711336600001
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
Indexed BySCIE
Scopus ID2-s2.0-85122518737
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Citation statistics
Document TypeReview article
CollectionDEPARTMENT OF PHYSICS AND CHEMISTRY
INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorYao, Yagang; Hong, Guo
Affiliation1.Henan Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, 436 Xian'ge Road, 455000, China
2.Institute of Applied Physics and Materials Engineering, University of Macau. Avenida da Universidade, Taipa, Macau SAR, 999078, China
3.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, Avenida da Universidade, Taipa, Macau SAR, 999078, China
4.National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210093, China
5.Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials, Suzhou Institute of Nano-Tech and Nano-Bionics, Nanchang, Chinese Academy of Sciences, Nanchang, 330200, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING;  Faculty of Science and Technology
Recommended Citation
GB/T 7714
Li, Chaowei,Wang, Litong,Zhang, Jingchao,et al. Roadmap on the protective strategies of zinc anodes in aqueous electrolyte[J]. Energy Storage Materials, 2022, 44, 104-135.
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