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Phase transformation induces plasticity with negligible damage in ceria-stabilized zirconia-based ceramics
Liens, Aléthéa1,2; Reveron, Helen1; Douillard, Thierry1; Blanchard, Nicholas3; Lughi, Vanni4; Sergo, Valter4,5; Laquai, René6; Müller, Bernd R.6; Bruno, Giovanni6; Schomer, Sven7; Fürderer, Tobias7; Adolfsson, Erik8; Courtois, Nicolas2; Swain, Michael9,10; Chevalier, Jérôme1
2020-01-15
Source PublicationActa Materialia
ISSN1359-6454
Volume183Pages:261-273
Abstract

Ceramics and their composites are in general brittle materials because they are predominantly made up of ionic and covalent bonds that avoid dislocation motion at room temperature. However, a remarkable ductile behavior has been observed on newly developed 11 mol.% ceria-stabilized zirconia (11Ce-TZP) composite containing fine alumina (8 vol.% AlO) and elongated strontium hexa-aluminate (8 vol.% SrAlO) grains. The as-synthesized composite also has shown full resistance to Low Temperature Degradation (LTD), relatively high strength and exceptionally high Weibull modulus, allowing its use in a broader range of biomedical applications. In this study, to deepen the understanding of plastic deformation in Ce-TZP based composites that could soon be used for manufacturing dental implants, different mechanical tests were applied on the material, followed by complete microstructural characterization. Distinct from pure Ce-TZP material or other zirconia-based ceramics developed in the past, the material here studied can be permanently strained without affecting the Young modulus, indicating that the ductile response of tested samples cannot be associated to damage occurrence. This ductility is related to the stress-induced tetragonal to monoclinic (t-m) zirconia phase transformation, analogue to Transformation-Induced Plasticity (TRIP) steels, where retained austenite is transformed to martensite. The aim of this study is to corroborate if the observed plasticity can be associated exclusively to the zirconia t-m phase transformation, or also to microcraking induced by the transformation. The t-m transformed-zones produced after bending and biaxial tests were examined by X-ray refraction and SEM/TEM coupled with Raman. The results revealed that the observed elastic-plastic behavior occurs without extensive microcracking, confirming a purely elastic-plastic behavior driven by the phase transformation (absence of damage).

KeywordCeramic Matrix Composite Ceria Phase Transformation Plasticity Zirconia
DOI10.1016/j.actamat.2019.10.046
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000506465100023
Scopus ID2-s2.0-85075192597
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Citation statistics
Document TypeJournal article
CollectionFaculty of Health Sciences
Corresponding AuthorReveron, Helen
Affiliation1.Université de Lyon-INSA de Lyon, MATEIS CNRS UMR 5510, Villeurbanne Cedex, 20 Avenue Albert Einstein, F-69621, France
2.ANTHOGYR, Sallanches, 2237 Avenue André Lasquin, 74700, France
3.Université de Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière, Villeurbanne, F-69622, France
4.Engineeering and Architecture Department, University of Trieste, Trieste, Via Valerio 6a, 34127, Italy
5.Faculty of Health Sciences, University of Macau, SAR Macau, China
6.BAM, Bundesanstalt für Materialforschung und -Prüfung, Berlin, Unter den Eichen 87, 12205, Germany
7.DOCERAM, MOESCHTER GROUP Holding GmbH & Co. KG, Dortmund, Hesslingsweg 65 – 67, 44309, Germany
8.Ceramic Materials, Swerea IVF AB, Mölndal, 431 53, Sweden
9.AMME, University of Sydney, 200, Australia
10.Engineering, Don State Technical University, Rostov-on Don, 344010, Russian Federation
Recommended Citation
GB/T 7714
Liens, Aléthéa,Reveron, Helen,Douillard, Thierry,et al. Phase transformation induces plasticity with negligible damage in ceria-stabilized zirconia-based ceramics[J]. Acta Materialia, 2020, 183, 261-273.
APA Liens, Aléthéa., Reveron, Helen., Douillard, Thierry., Blanchard, Nicholas., Lughi, Vanni., Sergo, Valter., Laquai, René., Müller, Bernd R.., Bruno, Giovanni., Schomer, Sven., Fürderer, Tobias., Adolfsson, Erik., Courtois, Nicolas., Swain, Michael., & Chevalier, Jérôme (2020). Phase transformation induces plasticity with negligible damage in ceria-stabilized zirconia-based ceramics. Acta Materialia, 183, 261-273.
MLA Liens, Aléthéa,et al."Phase transformation induces plasticity with negligible damage in ceria-stabilized zirconia-based ceramics".Acta Materialia 183(2020):261-273.
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