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Status | 已發表Published |
Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites | |
Chen, Shi1; Solanki, Ankur2,3; Pan, Jisheng4; Sum, Tze Chein2 | |
2019-09-01 | |
Source Publication | Coatings |
Volume | 9Issue:9 |
Abstract | With tremendous improvements in lead halide perovskite-based optoelectronic devices ranging from photovoltaics to light-emitting diodes, the instability problem stands as the primary challenge in their development. Among all factors, water is considered as one of the major culprits to the degradation of halide perovskite materials. For example, CHNHPbI (MAPbI) and CH(NH)PbI (FAPbI) decompose into PbI in days under ambient conditions. However, the intermediate changes of this degradation process are still not fully understood, especially the changes in early stage. Here we perform an in-situ investigation of the early-stage MAPbI and FAPbI degradation under high water vapor pressure. By probing the surface and bulk of perovskite samples using near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and XRD, our findings clearly show that PbI formation surprisingly initiates below the top surface or at grain boundaries, thus offering no protection as a water-blocking layer on surface or grain boundaries to slow down the degradation process. Meanwhile, significant morphological changes are observed in both samples after water vapor exposure. In comparison, the integrity of MAPbI film degrades much faster than the FAPbI film against water vapor. Pinholes and large voids are found in MAPbI film while only small number of pinholes can be found in FAPbI film. However, the FAPbI film suffers from its phase instability, showing a fast α-to-δ phase transition. Our results highlight the importance of the compositional and morphological changes in the early stage degradation in perovskite materials. |
Keyword | Degradation Halide Perovskite Morphology Pbi2 Formation Water |
DOI | 10.3390/coatings9090535 |
URL | View the original |
Language | 英語English |
WOS ID | WOS:000487973600030 |
Scopus ID | 2-s2.0-85072197551 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Chen, Shi |
Affiliation | 1.Institute of Applied Physics and Materials Engineering, University of Macau, Macao 2.Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore 3.Department of Science, School of Technology, Pandit Deendayal Petroleum University, Gandhiagar, 382007, India 4.Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis #08-03, 138634, Singapore |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Chen, Shi,Solanki, Ankur,Pan, Jisheng,et al. Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites[J]. Coatings, 2019, 9(9). |
APA | Chen, Shi., Solanki, Ankur., Pan, Jisheng., & Sum, Tze Chein (2019). Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites. Coatings, 9(9). |
MLA | Chen, Shi,et al."Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites".Coatings 9.9(2019). |
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