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Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites
Chen, Shi1; Solanki, Ankur2,3; Pan, Jisheng4; Sum, Tze Chein2
2019-09-01
Source PublicationCoatings
Volume9Issue:9
Abstract

With tremendous improvements in lead halide perovskite-based optoelectronic devices ranging from photovoltaics to light-emitting diodes, the instability problem stands as the primary challenge in their development. Among all factors, water is considered as one of the major culprits to the degradation of halide perovskite materials. For example, CHNHPbI (MAPbI) and CH(NH)PbI (FAPbI) decompose into PbI in days under ambient conditions. However, the intermediate changes of this degradation process are still not fully understood, especially the changes in early stage. Here we perform an in-situ investigation of the early-stage MAPbI and FAPbI degradation under high water vapor pressure. By probing the surface and bulk of perovskite samples using near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and XRD, our findings clearly show that PbI formation surprisingly initiates below the top surface or at grain boundaries, thus offering no protection as a water-blocking layer on surface or grain boundaries to slow down the degradation process. Meanwhile, significant morphological changes are observed in both samples after water vapor exposure. In comparison, the integrity of MAPbI film degrades much faster than the FAPbI film against water vapor. Pinholes and large voids are found in MAPbI film while only small number of pinholes can be found in FAPbI film. However, the FAPbI film suffers from its phase instability, showing a fast α-to-δ phase transition. Our results highlight the importance of the compositional and morphological changes in the early stage degradation in perovskite materials.

KeywordDegradation Halide Perovskite Morphology Pbi2 Formation Water
DOI10.3390/coatings9090535
URLView the original
Language英語English
WOS IDWOS:000487973600030
Scopus ID2-s2.0-85072197551
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Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorChen, Shi
Affiliation1.Institute of Applied Physics and Materials Engineering, University of Macau, Macao
2.Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore
3.Department of Science, School of Technology, Pandit Deendayal Petroleum University, Gandhiagar, 382007, India
4.Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis #08-03, 138634, Singapore
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Chen, Shi,Solanki, Ankur,Pan, Jisheng,et al. Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites[J]. Coatings, 2019, 9(9).
APA Chen, Shi., Solanki, Ankur., Pan, Jisheng., & Sum, Tze Chein (2019). Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites. Coatings, 9(9).
MLA Chen, Shi,et al."Compositional and morphological changes in water-induced early-stage degradation in lead halide perovskites".Coatings 9.9(2019).
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