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Stable UV-Pumped White Light-Emitting Diodes Based on Anthracene-Coated CsCu2I3
Liu, Weiwei1,2; Ng, Kar Wei2; Lin, Hao2; Dai, Ziyi2; Xu, Jincheng2; Su, Shichen3,4; Tang, Zikang2; Wang, Shuangpeng2
2021-06-17
Source PublicationJournal of Physical Chemistry C
ISSN1932-7447
Volume125Issue:23Pages:13076-13083
Abstract

Due to their excellent optical properties, all-inorganic halide perovskite nanocrystals (NCs) show great potential in lighting applications. However, the poor stability in a humid environment and strong ion exchange characteristics hinder the practical application of the exciting material in optoelectronic devices. In this work, we demonstrate the use of anthracene-coated CsCu2I3 (CsCu2I3@anthracene) NCs as efficient and stable color conversion phosphors in white light-emitting diodes (WLEDs). Synthesized via a facile solution process, the composite exhibits a high photoluminescence quantum yield of 27.3%. The efficient luminescence is enabled by the anthracene coating, which not only produces strong blue emission but also shields the yellow-emitting CsCu2I3 NCs from moisture and water. In addition, anthracene has minimal interactions with CsCu2I3 both chemically and optically. Therefore, by simple tailoring the mass ratio of the two components, one can easily combine the broad blue and yellow emissions to achieve white light with different correlated color temperatures (CCT) and long-term color stability. As a proof of concept, a WLED with a high color rendering index of 83, color coordinate of (0.31, 0.31), and CCT of 6718 K was obtained by combining CsCu2I3@anthracene with UV LED chips. Moreover, the fabricated WLED exhibits excellent color stability with operation voltage and time, attesting to the superior water resistance capability of the organic coating. The strategy proposed here can potentially further promote the application of lead-free inorganic perovskite NCs in the field of white light illumination.

DOI10.1021/acs.jpcc.1c04194
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000664312500064
Scopus ID2-s2.0-85108876214
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Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorTang, Zikang; Wang, Shuangpeng
Affiliation1.Department of Physics and Electronic Engineering, Yancheng Teachers University, Yancheng, 224002, China
2.MOE Joint Key Laboratory, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, 999078, Macao
3.Institute of Semiconductor Science and Technology, South China Normal University, Guangzhou, 510631, China
4.SCNU Qingyuan Institute of Science and Technology Innovation Co., Ltd., Qingyuan, 511517, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Liu, Weiwei,Ng, Kar Wei,Lin, Hao,et al. Stable UV-Pumped White Light-Emitting Diodes Based on Anthracene-Coated CsCu2I3[J]. Journal of Physical Chemistry C, 2021, 125(23), 13076-13083.
APA Liu, Weiwei., Ng, Kar Wei., Lin, Hao., Dai, Ziyi., Xu, Jincheng., Su, Shichen., Tang, Zikang., & Wang, Shuangpeng (2021). Stable UV-Pumped White Light-Emitting Diodes Based on Anthracene-Coated CsCu2I3. Journal of Physical Chemistry C, 125(23), 13076-13083.
MLA Liu, Weiwei,et al."Stable UV-Pumped White Light-Emitting Diodes Based on Anthracene-Coated CsCu2I3".Journal of Physical Chemistry C 125.23(2021):13076-13083.
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