Residential College | false |
Status | 已發表Published |
A "pDMS-in-water" emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature | |
Ge, Mingzheng1; Cao, Chunyan2; Liang, Fanghua1; Liu, Rong1; Zhang, Yu1; Zhang, Wei1; Zhu, Tianxue3; Yi, Bo2; Tang, Yuxin4; Lai, Yuekun3 | |
2020-01 | |
Source Publication | Nanoscale Horizons |
ISSN | 2055-6756 |
Volume | 5Issue:1Pages:65-73 |
Abstract | It is highly challenging to construct a durable superhydrophobic coating for practical applications since the coating is easily destroyed by mechano-chemical attack. To address this issue, a "PDMS-in-water" emulsion approach is for the first time adopted to design a mechanochemically robust superhydrophobic cotton fabric with intelligent self-healing nature, without using any fluorine-containing components. With this approach, PDMS molecules firstly penetrate into the cotton fiber, and then graft onto the surface of the cotton fabric with a strong binding force, creating hierarchical rough structures and lowering the surface energy simultaneously. Benefitting from this design, the PDMS@cotton fabric exhibits high superhydrophobicity with a water contact angle over 155°, surpassing all the PDMS-in-organic solvent based approaches. Impressively, the surface repairs its superhydrophobicity throughout the whole lifetime though damaged by machine washing or abrasion (>100 cycles), due to the self-diffusion process of PDMS molecules from the inner part to the outer surface of the cotton fibers to minimize surface free energy. Besides, the superhydrophobic coatings display superior chemical stability in strongly acidic and alkaline solution, and maintain similar textile physical properties of the cotton fabric, such as elongation at break, tensile strength, etc. Our environment-friendly "PDMS-in-water" approach can be easily integrated into industrial textile finishing treatment and is promising to apply to various substrates with robust superhydrophobic surfaces. |
DOI | 10.1039/c9nh00519f |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:000502785500017 |
Scopus ID | 2-s2.0-85077493453 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Zhang, Wei; Tang, Yuxin; Lai, Yuekun |
Affiliation | 1.School of Textile and Clothing, Natl. and Loc. Joint Engineering Research Center of Technical Fiber Composites for Safety and Health, Nantong University, Nantong, 226019, China 2.Department of Biomedical Sciences, City University of Hong Kong, 999077, China 3.National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China 4.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, China |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Ge, Mingzheng,Cao, Chunyan,Liang, Fanghua,et al. A "pDMS-in-water" emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature[J]. Nanoscale Horizons, 2020, 5(1), 65-73. |
APA | Ge, Mingzheng., Cao, Chunyan., Liang, Fanghua., Liu, Rong., Zhang, Yu., Zhang, Wei., Zhu, Tianxue., Yi, Bo., Tang, Yuxin., & Lai, Yuekun (2020). A "pDMS-in-water" emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature. Nanoscale Horizons, 5(1), 65-73. |
MLA | Ge, Mingzheng,et al."A "pDMS-in-water" emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature".Nanoscale Horizons 5.1(2020):65-73. |
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