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Elementary models of the "flux driven anti-ripening" during nanobelt growth
Gusak, Andriy1; Huriev, Yaroslav1; Malyi, Oleksandr I.2; Tang, Yuxin3
2020-05-07
Source PublicationPhysical Chemistry Chemical Physics
ISSN1463-9076
Volume22Issue:17Pages:9740-9748
Other Abstract

A stirring solution hydrothermal approach is widely used to rationally grow elongated oxide nanostructures with controllable aspect ratios. Depending on the synthesis conditions, the following are observed: (i) no nanostructure formation (the system exists as a pure liquid), (ii) formation of nanostructure starting from a critical powder/initial volume of the liquid solution, and (iii) monotonic increase in the nanostructure's aspect ratio (towards asymptotic value) with stirring rate. Despite these experimental observations, the theoretical understanding of the process is limited. Herein, using an athermal ballistic atomic jump model, we develop a phenomenological theory of nanostructure growth under different stirring rates, demonstrating the conditions necessary for breaking the equilibrium Wulff shape, the formation of elongated one-dimensional structures, and explaining regimes (i-iii) reported experimentally. Moreover, the comparison of the phenomenological models without and with the account of ripening effects in the open ensemble of nanowires under stirring provides the theoretical guidance for the controllable growth of elongated nanostructures by the stirring solution hydrothermal approach.

DOI10.1039/c9cp06337d
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000532479300057
PublisherROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Scopus ID2-s2.0-85084271391
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Document TypeJournal article
CollectionUniversity of Macau
Corresponding AuthorTang, Yuxin
Affiliation1.Department of Physics, Cherkasy National University, Cherkasy, 18000, Ukraine
2.Renewable and Sustainable Energy Institute, University of Colorado, Boulder, 80309, United States
3.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, 999078, Macao
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Gusak, Andriy,Huriev, Yaroslav,Malyi, Oleksandr I.,et al. Elementary models of the "flux driven anti-ripening" during nanobelt growth[J]. Physical Chemistry Chemical Physics, 2020, 22(17), 9740-9748.
APA Gusak, Andriy., Huriev, Yaroslav., Malyi, Oleksandr I.., & Tang, Yuxin (2020). Elementary models of the "flux driven anti-ripening" during nanobelt growth. Physical Chemistry Chemical Physics, 22(17), 9740-9748.
MLA Gusak, Andriy,et al."Elementary models of the "flux driven anti-ripening" during nanobelt growth".Physical Chemistry Chemical Physics 22.17(2020):9740-9748.
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