Residential College | false |
Status | 已發表Published |
Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors | |
Kwun Nam Hui1; Kwan San Hui2; Zikang Tang1; V.V. Jadhav3; Qi Xun Xia3 | |
2016-10-31 | |
Source Publication | Journal of Power Sources |
ISSN | 0378-7753 |
Volume | 330Pages:195-203 |
Abstract | Hierarchical chestnut-like manganese cobalt oxide (MnCo2O4) nanoneedles (NNs) are successfully grown on nickel foam using a facile and cost-effective hydrothermal method. High resolution TEM image further verifies that the chestnut-like MnCo2O4 structure is assembled by numerous 1D MnCo2O4 nanoneedles, which are formed by numerous interconnected MnCo2O4 nanoparticles with grain diameter of ∼10 nm. The MnCo2O4 electrode exhibits high specific capacitance of 1535 F g−1 at 1 A g−1 and good rate capability (950 F g−1 at 10 A g−1) in a 6 M KOH electrolyte. An asymmetric supercapacitor is fabricated using MnCo2O4 NNs on Ni foam (MnCo2O4 NNs/NF) as the positive electrode and graphene/NF as the negative electrode. The device shows an operation voltage of 1.5 V and delivers a high energy density of ∼60.4 Wh kg−1 at a power density of ∼375 W kg−1. Moreover, the device exhibits an excellent cycling stability of 94.3% capacitance retention after 12000 cycles at 30 A g−1. This work demonstrates that hierarchical chestnut-like MnCo2O4 NNs could be a promising electrode for the high performance energy storage devices. |
Keyword | Mnco2o4 Nanoneedles Graphene Hydrothermal Asymmetric Supercapacitor |
DOI | 10.1016/j.jpowsour.2016.08.116 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary |
WOS ID | WOS:000385329400024 |
Publisher | ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS |
The Source to Article | Scopus |
Scopus ID | 2-s2.0-84986559316 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Kwun Nam Hui; Kwan San Hui |
Affiliation | 1.Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau, China 2.School of Mathematics, University of East Anglia, Norwich, NR4 7TJ, United Kingdom 3.School of Materials Science and Engineering, Pusan National University, San 30 Jangjeon-dong, Geumjeong-gu, Busan 609-735, Republic of Korea |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Kwun Nam Hui,Kwan San Hui,Zikang Tang,et al. Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors[J]. Journal of Power Sources, 2016, 330, 195-203. |
APA | Kwun Nam Hui., Kwan San Hui., Zikang Tang., V.V. Jadhav., & Qi Xun Xia (2016). Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors. Journal of Power Sources, 330, 195-203. |
MLA | Kwun Nam Hui,et al."Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors".Journal of Power Sources 330(2016):195-203. |
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