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Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors
Kwun Nam Hui1; Kwan San Hui2; Zikang Tang1; V.V. Jadhav3; Qi Xun Xia3
2016-10-31
Source PublicationJournal of Power Sources
ISSN0378-7753
Volume330Pages:195-203
Abstract

Hierarchical chestnut-like manganese cobalt oxide (MnCo2O4) nanoneedles (NNs) are successfully grown on nickel foam using a facile and cost-effective hydrothermal method. High resolution TEM image further verifies that the chestnut-like MnCo2O4 structure is assembled by numerous 1D MnCo2O4 nanoneedles, which are formed by numerous interconnected MnCo2O4 nanoparticles with grain diameter of ∼10 nm. The MnCo2O4 electrode exhibits high specific capacitance of 1535 F g−1 at 1 A g−1 and good rate capability (950 F g−1 at 10 A g−1) in a 6 M KOH electrolyte. An asymmetric supercapacitor is fabricated using MnCo2O4 NNs on Ni foam (MnCo2O4 NNs/NF) as the positive electrode and graphene/NF as the negative electrode. The device shows an operation voltage of 1.5 V and delivers a high energy density of ∼60.4 Wh kg−1 at a power density of ∼375 W kg−1. Moreover, the device exhibits an excellent cycling stability of 94.3% capacitance retention after 12000 cycles at 30 A g−1. This work demonstrates that hierarchical chestnut-like MnCo2O4 NNs could be a promising electrode for the high performance energy storage devices.

KeywordMnco2o4 Nanoneedles Graphene Hydrothermal Asymmetric Supercapacitor
DOI10.1016/j.jpowsour.2016.08.116
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000385329400024
PublisherELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS
The Source to ArticleScopus
Scopus ID2-s2.0-84986559316
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorKwun Nam Hui; Kwan San Hui
Affiliation1.Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau, China
2.School of Mathematics, University of East Anglia, Norwich, NR4 7TJ, United Kingdom
3.School of Materials Science and Engineering, Pusan National University, San 30 Jangjeon-dong, Geumjeong-gu, Busan 609-735, Republic of Korea
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Kwun Nam Hui,Kwan San Hui,Zikang Tang,et al. Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors[J]. Journal of Power Sources, 2016, 330, 195-203.
APA Kwun Nam Hui., Kwan San Hui., Zikang Tang., V.V. Jadhav., & Qi Xun Xia (2016). Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors. Journal of Power Sources, 330, 195-203.
MLA Kwun Nam Hui,et al."Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors".Journal of Power Sources 330(2016):195-203.
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