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Effects of Material Dimensionality on the Optical Properties of CsPbBr3 Nanomaterials
Zhang,Xuanyu1; Gao,Xian2; Pang,Guotao2; He,Tingchao3; Xing,Guichuan4; Chen,Rui2
2019-11
Source PublicationJournal of Physical Chemistry C
ISSN1932-7447
Volume123Issue:47Pages:28893-28897
Abstract

Inorganic perovskites such as CsPbBr have attracted intensive research attention due to their excellent thermal stability and high photoluminescence quantum efficiency. With the decrease of the material's dimension, quantum confinement effects will take place, which will induce many interesting properties. Here, quasi two-dimensional perovskite nanoplatelets (NPLs) and three-dimensional perovskite nanocrystals (NCs) have been grown, and their optical properties have been compared and discussed. It is interesting to find that the photon energy of CsPbBr NPLs hardly changes with temperature due to strong electron-phonon interaction. At the same time, the strong quantum confinement effect results in a smaller Stokes shift and a faster fluorescence lifetime. In addition, although the NPLs have many surface defects, they exhibit a relatively strong negative thermal quenching effect of emission. These results demonstrate the unique optical properties of perovskite NPLs that can pave the way for future nanoscale devices.

DOI10.1021/acs.jpcc.9b08606
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000500417600043
PublisherAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Scopus ID2-s2.0-85075580969
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorXing,Guichuan; Chen,Rui
Affiliation1.Key Laboratory of Flexible Electronics,Institute of Advanced Materials,Jiangsu National Synergetic Innovation Center for Advanced Materials,Nanjing Tech University,Nanjing,30 South Puzhu Road,211816,China
2.Department of Electrical and Electronic Engineering,Southern University of Science and Technology,Shenzhen,518055,China
3.College of Physics and Optoelectronic Engineering,Shenzhen University,Shenzhen,518060,China
4.Institute of Applied Physics and Materials Engineering,University of Macau,Taipa,Avenida da Universidade,Macao
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Zhang,Xuanyu,Gao,Xian,Pang,Guotao,et al. Effects of Material Dimensionality on the Optical Properties of CsPbBr3 Nanomaterials[J]. Journal of Physical Chemistry C, 2019, 123(47), 28893-28897.
APA Zhang,Xuanyu., Gao,Xian., Pang,Guotao., He,Tingchao., Xing,Guichuan., & Chen,Rui (2019). Effects of Material Dimensionality on the Optical Properties of CsPbBr3 Nanomaterials. Journal of Physical Chemistry C, 123(47), 28893-28897.
MLA Zhang,Xuanyu,et al."Effects of Material Dimensionality on the Optical Properties of CsPbBr3 Nanomaterials".Journal of Physical Chemistry C 123.47(2019):28893-28897.
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