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Sputtered Indium-Zinc Oxide for Buffer Layer Free Semitransparent Perovskite Photovoltaic Devices in Perovskite/Silicon 4T-Tandem Solar Cells
Zhiqin Ying1,2; Yudong Zhu1; Xiyuan Feng1,2; Jingwei Xiu1; Rui Zhang3; Xuhang Ma3; Yunsheng Deng3; Hui Pan2; Zhubing He1
2020-12-06
Source PublicationAdvanced Materials Interfaces
ISSN2196-7350
Volume8Issue:6Pages:2001604
Abstract

Rear transparent electrode (RTE) dominates the quality of semitransparent solar cells, which determines the overall performance of tandem devices as the top cells. Here, sputtering deposited indium-zinc oxide (IZO) is demonstrated as effective RTE for buffer layer free semitransparent perovskite solar cell (PSC). It is revealed that the vacuum-evaporated electron-transport layer (C/BCP, v-ETL) has better tolerance of the bombardment in the deposition process of IZO and hence superior device performance compared to the solution-processed ETL (PCBM/BCP, s-ETL). Systematical characterizations evidence that the ETL surface potential shifts at the ETL/IZO interface rather than the surface morphology variation accounts for the device performance difference. By further optimizing the thickness of BCP and perovskite layers, the semitransparent PSC exhibits the best conversion efficiency of 16.23% as well as a high transmittance of 39.46% in the wavelength span from 300 to 1200 nm. By employing the optimized semitransparent PSC as the top cell in a four-terminal perovskite/c-silicon tandem solar cell, a combined conversion efficiency of 24.60% is achieved. This work highlights the use of sputtered IZO in the combination of IZO/C60 effectively for high-performance semitransparent devices.

KeywordBuffer Layers Four Terminal Tandem Solar Cells Indium-zinc Oxide Perovskite Solar Cells Semitransparent Solar Cells
DOI10.1002/admi.202001604
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Materials Science
WOS SubjectChemistry, Multidisciplinary ; Materials Science, Multidisciplinary
WOS IDWOS:000596097700001
Scopus ID2-s2.0-85097209905
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Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorHui Pan; Zhubing He
Affiliation1.Department of Materials Science and Engineering,Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG),Southern University of Science and Technology,Shenzhen,No. 1088, Xueyuan Rd.,518055,China
2.Joint Key Laboratory of the Ministry of Education,Institute of Applied Physics and Materials Engineering,University of Macau,999078,Macao
3.Core Research Facilities,Southern University of Science and Technology,Shenzhen,No. 1088, Xueyuan Rd.,518055,China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Zhiqin Ying,Yudong Zhu,Xiyuan Feng,et al. Sputtered Indium-Zinc Oxide for Buffer Layer Free Semitransparent Perovskite Photovoltaic Devices in Perovskite/Silicon 4T-Tandem Solar Cells[J]. Advanced Materials Interfaces, 2020, 8(6), 2001604.
APA Zhiqin Ying., Yudong Zhu., Xiyuan Feng., Jingwei Xiu., Rui Zhang., Xuhang Ma., Yunsheng Deng., Hui Pan., & Zhubing He (2020). Sputtered Indium-Zinc Oxide for Buffer Layer Free Semitransparent Perovskite Photovoltaic Devices in Perovskite/Silicon 4T-Tandem Solar Cells. Advanced Materials Interfaces, 8(6), 2001604.
MLA Zhiqin Ying,et al."Sputtered Indium-Zinc Oxide for Buffer Layer Free Semitransparent Perovskite Photovoltaic Devices in Perovskite/Silicon 4T-Tandem Solar Cells".Advanced Materials Interfaces 8.6(2020):2001604.
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