An efficient option pricing method based on the Fourier cosine series expansion was proposed by Fang and Oosterlee [A novel option pricing method based on Fourier-cosine series expansions, SIAM J. Sci. Comput. 31 (2008), pp. 826-848], and recently it has been used in two-dimensional cases by Ruijter and Oosterlee [Two-dimensional Fourier cosine series expansion method for pricing financial options, SIAM J. Sci. Comput. 34 (2012), pp. B642-B671]. In this paper, we consider a modification of the Fourier sine-sine expansion, whereby in [-1, 1] the sin(π nx) functions are replaced by sin(π(n-)x), n≥1, for pricing rainbow options. Feasible approaches for obtaining the pricing formulae are presented. A numerical comparison and a flexible and general error analysis are considered to prove the effectiveness of the method. Practical applications to basket options and correlation options under different models are also given. They indicate satisfactory convergence and efficiency as expected.