Residential College | false |
Status | 已發表Published |
Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells | |
Dandan Zhao1,2; Yinghui Wu1; Bao Tu1,2; Guichuan Xing2; Haifeng Li2; Zhubing He1 | |
2019-02 | |
Source Publication | Nanomaterials |
ISSN | 2079-4991 |
Volume | 9Issue:2 |
Abstract | Although a compact holes-transport-layer (HTL) film has always been deemed mandatory for perovskite solar cells (PSCs), the impact their compactness on the device performance has rarely been studied in detail. In this work, based on a device structure of FTO/CIGS/perovskite/PCBM/ZrAcac/Ag, that effect was systematically investigated with respect to device performance along with photo-physics characterization tools. Depending on spin-coating speed, the grain size and coverage ratio of those CIGS films on FTO substrates can be tuned, and this can result in different hole transfer efficiencies at the anode interface. At a speed of 4000 r.p.m., the band level offset between the perovskite and CIGS modified FTO was reduced to a minimum of 0.02 eV, leading to the best device performance, with conversion efficiency of 15.16% and open-circuit voltage of 1.04 V, along with the suppression of hysteresis. We believe that the balance of grain size and coverage ratio of CIGS interlayers can be tuned to an optimal point in the competition between carrier transport and recombination at the interface based on the proposed mechanism. This paper definitely deepens our understanding of the hole transfer mechanism at the interface of PSC devices, and facilitates future design of high-performance devices. |
Keyword | Holes Transport Layer Compactness Hole Transfer Recombination Cu-in-ga-s Perovskite Solar Cells |
DOI | 10.3390/nano9020286 |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Science & Technology - Other Topics ; Chemistry ; Physics ; Materials Science |
WOS Subject | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
WOS ID | WOS:000460806700155 |
Publisher | MDPI, ST ALBAN-ANLAGE 66, CH-4052 BASEL, SWITZERLAND |
Scopus ID | 2-s2.0-85071053140 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | DEPARTMENT OF PHYSICS AND CHEMISTRY INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Zhubing He |
Affiliation | 1.Department of Materials Science and Engineering, Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG), Southern University of Science and Technology, No. 1088, Xueyuan Rd., Shenzhen 518055, Guangdong, China; [email protected] (D.Z.); 2.Institute of Applied Physics and Materials Engineering, University of Macau, Macau SAR 999078, China; |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Dandan Zhao,Yinghui Wu,Bao Tu,et al. Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells[J]. Nanomaterials, 2019, 9(2). |
APA | Dandan Zhao., Yinghui Wu., Bao Tu., Guichuan Xing., Haifeng Li., & Zhubing He (2019). Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells. Nanomaterials, 9(2). |
MLA | Dandan Zhao,et al."Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells".Nanomaterials 9.2(2019). |
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