A flame retardant containing phosphorus and nitrogen was prepared. This halogen-free flame retardant was blended with polypropylene (PP) by hot melting to improve the flame-retardant capability and thermal stability of the composites. Fourier transform infrared spectroscopy, energy dispersive X-ray measurements, thermogravimetric analysis, limiting oxygen index (LOI) measurements, and UL-94 measurements were applied to characterize the structure and thermal and flame-retardant properties of the composites. When the flame-retardant concentration was 40 wt%, the LOI value of the composite was 40, passing the V-0 rating of the UL-94 test. The LOI and UL-94 data showed the composites have an excellent flame-retardant property. For a kinetic study of thermal degradation, Ozawa's method was applied to calculate the activation energies of pure PP and the composites. Analytical results indicate that the composites had higher values, meaning they have better thermal stability. © The Author(s) 2012.