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Preparation of MgxZn1-xO nanofibers using PVP nanofibers as templates by atom layer deposition and their optical properties
Jia H.-M.1; Tang J.-L.1; Fang X.1; Wang S.-P.2; Zhao H.-F.2; Fang D.1; Wang X.-H.1; Fang F.1; Li J.-H.1; Chu X.-Y.1; Wei Z.-P.1; Ma X.-H.1; Xu L.1
2014-12-01
Source PublicationSPECTROSCOPY AND SPECTRAL ANALYSIS
ISSN1000-0593
Volume34Issue:12Pages:3197-3200
Abstract

In the present paper, MgZnO nanofibers with different doping concentration were prepared by atom layer deposition (ALD) using polyvinyl pyrrolidone (PVP) nanofibers as template, which were synthesized by electrospinning. The influence of different Mg doping concentration on the structure and optical properties of composite nanofibers was investigated. The samples were characterized by field emission scanning electron microscopy (FESEM), ultraviolet visible (UV-Vis)absorption spectroscopy and photoluminescence (PL) spectra. The doping of Mg did not change the morphologies of ZnO nanofibers, the morphologies of all the samples were very similar while the diameter of MgZnO-PVP composite nanofibers became larger after doping. With the increase in the Mg doping concentration, the absorption edge shifted to larger energy side, revealing the band gap tenability of MgZnO nanofibers. Meanwhile, a significant blue shift of the UV emission peak from 377 to 362 nm was observed in PL spectra. Compared with ZnO-PVP composite nanofibers, the UV emission intensity of MgZnO-PVP composite nanofibers was much stronger. Component control MgZnO nanofibers can be synthesized by this method. The doping of Mg elements in ZnO can effectively improve the band gap of ZnO-PVP nanofibers and the intensity of UV emission.

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In the present paper, MgZnO nanofibers with different doping concentration were prepared by atom layer deposition (ALD) using polyvinyl pyrrolidone (PVP) nanofibers as template, which were synthesized by electrospinning. The influence of different Mg doping concentration on the structure and optical properties of composite nanofibers was investigated. The samples were characterized by field emission scanning electron microscopy (FESEM), ultraviolet visible (UV-Vis)absorption spectroscopy and photoluminescence (PL) spectra. The doping of Mg did not change the morphologies of ZnO nanofibers, the morphologies of all the samples were very similar while the diameter of MgZnO-PVP composite nanofibers became larger after doping. With the increase in the Mg doping concentration, the absorption edge shifted to larger energy side, revealing the band gap tenability of MgZnO nanofibers. Meanwhile, a significant blue shift of the UV emission peak from 377 to 362 nm was observed in PL spectra. Compared with ZnO-PVP composite nanofibers, the UV emission intensity of MgZnO-PVP composite nanofibers was much stronger. Component control MgZnO nanofibers can be synthesized by this method. The doping of Mg elements in ZnO can effectively improve the band gap of ZnO-PVP nanofibers and the intensity of UV emission.

KeywordAld Composite Nanofibers Electrospinning Mgxzn1-xo Pvp Ald Composite Nanofibers Electrospinning Mgxzn1-xo Pvp
DOI10.3964/j.issn.1000-0593(2014)12-3197-04
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaSpectroscopy ; Spectroscopy
WOS SubjectSpectroscopy ; Spectroscopy
WOS IDWOS:000346224300007
Scopus ID2-s2.0-84916205138
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Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorJia H.-M.; Tang J.-L.; Fang X.
Affiliation1.Changchun University of Science and Technology
2.Changchun Institute of Optics Fine Mechanics and Physics Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Jia H.-M.,Tang J.-L.,Fang X.,et al. Preparation of MgxZn1-xO nanofibers using PVP nanofibers as templates by atom layer deposition and their optical properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(12), 3197-3200.
APA Jia H.-M.., Tang J.-L.., Fang X.., Wang S.-P.., Zhao H.-F.., Fang D.., Wang X.-H.., Fang F.., Li J.-H.., Chu X.-Y.., Wei Z.-P.., Ma X.-H.., & Xu L. (2014). Preparation of MgxZn1-xO nanofibers using PVP nanofibers as templates by atom layer deposition and their optical properties. SPECTROSCOPY AND SPECTRAL ANALYSIS, 34(12), 3197-3200.
MLA Jia H.-M.,et al."Preparation of MgxZn1-xO nanofibers using PVP nanofibers as templates by atom layer deposition and their optical properties".SPECTROSCOPY AND SPECTRAL ANALYSIS 34.12(2014):3197-3200.
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