In this paper, study on a new 0-3 type cement-based PZT (Lead Zirconate Titanate) composites is presented. Using a normal mixing and compacting method, up to 50vol% PZT ceramic powder could be incorporated into cement-based composites. The behaviors of the composites under different polarizing conditions are investigated. And the piezoelectric properties of cement-based PZT composites are evaluated both theoretically and experimentally. Moreover, the impendence spectrum of composites is studied to approve the electromechanical coupling behavior. It shows that cement-based PZT composites have some advantage to the polymer-based PZT composites. There is a good potential for application of 0-3 type cement-based piezoelectric composites in civil engineering.