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Is it possible to enhance Raman scattering of single-walled carbon nanotubes by metal particles during chemical vapor deposition?
Liu M.3; Xiang R.3; Cao W.3; Zeng H.3; Su Y.3; Gui X.3; Wu T.1; Maruyama S.4; Tang Z.3
2014
Source PublicationCarbon
ISSN00086223
Volume80Issue:1Pages:311-317
Abstract

We explore the possibility of using metal nano-particles to enhance the Raman scattering of single walled carbon nanotubes (SWCNTs) at high temperatures, with the aim of obtaining enhanced in situ Raman spectra of SWCNT during chemical vapor deposition (CVD). Particle position, metal type, film thickness, excitation wavelength are systematically optimized to meet the requirements for high temperature and in situ measurements. Au particles provide a weak but stable enhancement up to 1000 °C, while the enhancement factors of Ag particles decrease at elevated temperatures due to morphology change and metal evaporation. After the morphology relating effects are eliminated, surface enhanced Raman scattering (SERS) of SWCNT is confirmed to be almost temperature independent in our SWCNT-Ag/Au system. Finally, in situ enhanced spectra with identifiable RBM peaks are obtained in a realistic CVD growth of SWCNTs. The mechanism behind the relatively low enhancement factor is also discussed.

DOI10.1016/j.carbon.2014.08.069
URLView the original
Language英語English
WOS IDWOS:000344132400034
Scopus ID2-s2.0-84920592968
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionUniversity of Macau
Affiliation1.Shenzhen Institute of Advanced Technology
2.University of Tokyo
3.Sun Yat-Sen University
4.Hong Kong University of Science and Technology
Recommended Citation
GB/T 7714
Liu M.,Xiang R.,Cao W.,et al. Is it possible to enhance Raman scattering of single-walled carbon nanotubes by metal particles during chemical vapor deposition?[J]. Carbon, 2014, 80(1), 311-317.
APA Liu M.., Xiang R.., Cao W.., Zeng H.., Su Y.., Gui X.., Wu T.., Maruyama S.., & Tang Z. (2014). Is it possible to enhance Raman scattering of single-walled carbon nanotubes by metal particles during chemical vapor deposition?. Carbon, 80(1), 311-317.
MLA Liu M.,et al."Is it possible to enhance Raman scattering of single-walled carbon nanotubes by metal particles during chemical vapor deposition?".Carbon 80.1(2014):311-317.
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