Residential College | false |
Status | 已發表Published |
Investigation of water adsorption and hygroscopicity of atmospherically relevant particles using a commercial vapor sorption analyzer | |
Gu Wenjun1,4; Li Yongjie2; Zhu Jianxi3; Jia Xiaohong1,4; Lin Qinhao1; Zhang Guohua1; Ding Xiang1; Song Wei1; Bi Xinhui1; Wang Xinming1,5; Tang Mingjin1 | |
2017-10-19 | |
Source Publication | ATMOSPHERIC MEASUREMENT TECHNIQUES |
ISSN | 1867-1381 |
Volume | 10Issue:10Pages:3821-3832 |
Abstract | Water adsorption and hygroscopicity are among the most important physicochemical properties of aerosol particles, largely determining their impacts on atmospheric chemistry, radiative forcing, and climate. Measurements of water adsorption and hygroscopicity of nonspherical particles under subsaturated conditions are nontrivial because many widely used techniques require the assumption of particle sphericity. In this work we describe a method to directly quantify water adsorption and mass hygroscopic growth of atmospheric particles for temperature in the range of 5-30 degrees C, using a commercial vapor sorption analyzer. A detailed description of instrumental configuration and experimental procedures, including relative humidity (RH) calibration, is provided first. It is then demonstrated that for (NH4)2SO4 and NaCl, deliquescence relative humidities and mass hygroscopic growth factors measured using this method show good agreements with experimental and/or theoretical data from literature. To illustrate its ability to measure water uptake by particles with low hygroscopicity, we used this instrument to investigate water adsorption by CaSO4 center dot 2H2O as a function of RH at 25 degrees C. The mass hygroscopic growth factor of CaSO4 center dot 2H2O at 95% RH, relative to that under dry conditions (RH < 1 %), was determined to be (0.450 +/- 0.004)% (1 sigma). In addition, it is shown that this instrument can reliably measure a relative mass change of 0.025 %. Overall, we have demonstrated that this commercial instrument provides a simple, sensitive, and robust method to investigate water adsorption and hygroscopicity of atmospheric particles. |
DOI | 10.5194/amt-10-3821-2017 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Meteorology & Atmospheric Sciences |
WOS Subject | Meteorology & Atmospheric Sciences |
WOS ID | WOS:000413216200001 |
Publisher | COPERNICUS GESELLSCHAFT MBH |
The Source to Article | WOS |
Scopus ID | 2-s2.0-85031795261 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | DEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING |
Corresponding Author | Tang Mingjin |
Affiliation | 1.State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China 2.Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Avenida da Universidade, Taipa, Macau, China 3.CAS Key Laboratory of Mineralogy and Metallogeny and Guangdong Provincial Key Laboratory of Mineral Physics and Material Research and Development, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China 4.University of Chinese Academy of Sciences, Beijing 100049, China 5.Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China |
Recommended Citation GB/T 7714 | Gu Wenjun,Li Yongjie,Zhu Jianxi,et al. Investigation of water adsorption and hygroscopicity of atmospherically relevant particles using a commercial vapor sorption analyzer[J]. ATMOSPHERIC MEASUREMENT TECHNIQUES, 2017, 10(10), 3821-3832. |
APA | Gu Wenjun., Li Yongjie., Zhu Jianxi., Jia Xiaohong., Lin Qinhao., Zhang Guohua., Ding Xiang., Song Wei., Bi Xinhui., Wang Xinming., & Tang Mingjin (2017). Investigation of water adsorption and hygroscopicity of atmospherically relevant particles using a commercial vapor sorption analyzer. ATMOSPHERIC MEASUREMENT TECHNIQUES, 10(10), 3821-3832. |
MLA | Gu Wenjun,et al."Investigation of water adsorption and hygroscopicity of atmospherically relevant particles using a commercial vapor sorption analyzer".ATMOSPHERIC MEASUREMENT TECHNIQUES 10.10(2017):3821-3832. |
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