Critical Effects of Insoluble Additives in Liquid Electrolytes for Metal Batteries

doi:10.1002/smll.202312124

Residential College	false
Status	即將出版Forthcoming
	Critical Effects of Insoluble Additives in Liquid Electrolytes for Metal Batteries
	Xu, Zhu 1; Wang, Kexuan 1; Li, Heng 1,2; Wang, Huibo 1; Ge, Mingzheng 1; Zhang, Yanyan 3; Tang, Yuxin 3; Chen, Shi 1
	2024
Source Publication	Small
ISSN	1613-6810
Abstract	Rechargeable metal batteries have received widespread attention due to their high energy density by using pure metal as the anode. However, there are still many fundamental problems that need to be solved before approaching practical applications. The critical ones are low charge/discharge current due to slow ion transport, short cycle lifetime due to poor anode/cathode stability, and unsatisfied battery safety. To tackle these problems, various strategies have been suggested. Among them, electrolyte additive is one of the most widely used strategies. Most of the additives currently studied are soluble, but their reliability is questionable, and they can easily affect the electrochemical process, causing unwanted battery performance decline. On the contrary, insoluble additives with excellent chemical stability, high mechanical strength, and dimensional tunability have attracted considerable research exploration recently. However, there is no timely review on insoluble additives in metal batteries yet. This review summarizes various functions of insoluble additives: ion transport modulation, metal anode protection, cathode amelioration, as well as battery safety enhancement. Future research directions and challenges for insoluble solid additives are also proposed. It is expected this review will stimulate inspiration and arouse extensive studies on further improvement in the overall performance of metal batteries.
Keyword	battery safety electrode stability insoluble additives ion transport metal batteries
DOI	10.1002/smll.202312124
URL	View the original
Language	英語English
Scopus ID	2-s2.0-85192940748
Fulltext Access	View Full-Text via DOI View Full-Text via Web of Science View Full-Text via Scopus
Citation statistics
Document Type	Journal article
Collection	University of Macau
Affiliation	1.Institute of Applied Physics and Materials Engineering, University of Macau, SAR, 999078, Macao 2.State Key Laboratory of High-Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China 3.College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
First Author Affilication	INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation GB/T 7714	Xu, Zhu,Wang, Kexuan,Li, Heng,et al. Critical Effects of Insoluble Additives in Liquid Electrolytes for Metal Batteries[J]. Small, 2024.
APA	Xu, Zhu., Wang, Kexuan., Li, Heng., Wang, Huibo., Ge, Mingzheng., Zhang, Yanyan., Tang, Yuxin., & Chen, Shi (2024). Critical Effects of Insoluble Additives in Liquid Electrolytes for Metal Batteries. Small.
MLA	Xu, Zhu,et al."Critical Effects of Insoluble Additives in Liquid Electrolytes for Metal Batteries".Small (2024).

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