Residential College | false |
Status | 已發表Published |
Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution | |
Yang, Junge1,2,3; Feng, Jinxian1; Cao, Youpeng1; Xiao, Yuxuan1; Qiao, Lulu1; An, Keyu1; Yang, Jiao1; Peng, Jing2,3; Pan, Hui1,4; Cheng, Hui Ming2,3,5 | |
2024-08 | |
Source Publication | Advanced Functional Materials |
ISSN | 1616-301X |
Pages | 2411081 |
Abstract | An efficient and stable electrocatalyst is key for the production of green hydrogen using water electrolysis. However, the weak dissociation ability of Pt-based catalysts, resulting in slow kinetics severely hampers its applications in alkali medium. Herein, a simple “coincident reduction” strategy is reported to grow highly dispersed Ru-Pt heterogeneous bimetallic nanoparticles on reduced graphene oxide (RuxPty@rGO) for efficient pH-universal hydrogen evolution. RuxPty@rGO has superior catalytic activity at all pH values due to the synergistic effect between Ru and Pt and the ultra-small nanoparticle. In particular, the catalyst with 13.6 wt% of noble metal (RuxPty@rGO) has low overpotentials of 9, 6, and 36 mV at 10 mA cm-2 in 1 m KOH, 0.5 m H2SO4 and 1 m phosphate buffer solution (PBS), respectively, which outperformances monometallic counterparts and comparable to the best bimetallic catalysts ever reported. The catalyst is highly stable because of the strong bonding between the bimetallic nanoparticle and rGO. Mechanism studies show that RuxPty@rGO has a faster Volmer–Tafel mechanism in alkali, high-efficient H transfer and increased H adsorption ability in acid, resulting in superior reaction kinetics. This work provides a new route for mass production of high-performance catalysts for practical applications at all pH values. |
Keyword | Electrocatalyst Graphene Oxide Hydrogen Evolution Reaction Ph-universal Ru-pt Nanoparticle |
DOI | 10.1002/adfm.202411081 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
WOS ID | WOS:001296778700001 |
Publisher | WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY |
Scopus ID | 2-s2.0-85201801899 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | Faculty of Science and Technology INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING DEPARTMENT OF PHYSICS AND CHEMISTRY |
Corresponding Author | Peng, Jing; Pan, Hui; Cheng, Hui Ming |
Affiliation | 1.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao 2.Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China 3.Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China 4.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, 999078, Macao 5.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING; Faculty of Science and Technology |
Recommended Citation GB/T 7714 | Yang, Junge,Feng, Jinxian,Cao, Youpeng,et al. Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution[J]. Advanced Functional Materials, 2024, 2411081. |
APA | Yang, Junge., Feng, Jinxian., Cao, Youpeng., Xiao, Yuxuan., Qiao, Lulu., An, Keyu., Yang, Jiao., Peng, Jing., Pan, Hui., & Cheng, Hui Ming (2024). Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution. Advanced Functional Materials, 2411081. |
MLA | Yang, Junge,et al."Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution".Advanced Functional Materials (2024):2411081. |
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