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Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution
Yang, Junge1,2,3; Feng, Jinxian1; Cao, Youpeng1; Xiao, Yuxuan1; Qiao, Lulu1; An, Keyu1; Yang, Jiao1; Peng, Jing2,3; Pan, Hui1,4; Cheng, Hui Ming2,3,5
2024-08
Source PublicationAdvanced Functional Materials
ISSN1616-301X
Pages2411081
Abstract

An efficient and stable electrocatalyst is key for the production of green hydrogen using water electrolysis. However, the weak dissociation ability of Pt-based catalysts, resulting in slow kinetics severely hampers its applications in alkali medium. Herein, a simple “coincident reduction” strategy is reported to grow highly dispersed Ru-Pt heterogeneous bimetallic nanoparticles on reduced graphene oxide (RuxPty@rGO) for efficient pH-universal hydrogen evolution. RuxPty@rGO has superior catalytic activity at all pH values due to the synergistic effect between Ru and Pt and the ultra-small nanoparticle. In particular, the catalyst with 13.6 wt% of noble metal (RuxPty@rGO) has low overpotentials of 9, 6, and 36 mV at 10 mA cm-2 in 1 m KOH, 0.5 m H2SO4 and 1 m phosphate buffer solution (PBS), respectively, which outperformances monometallic counterparts and comparable to the best bimetallic catalysts ever reported. The catalyst is highly stable because of the strong bonding between the bimetallic nanoparticle and rGO. Mechanism studies show that RuxPty@rGO has a faster Volmer–Tafel mechanism in alkali, high-efficient H transfer and increased H adsorption ability in acid, resulting in superior reaction kinetics. This work provides a new route for mass production of high-performance catalysts for practical applications at all pH values.

KeywordElectrocatalyst Graphene Oxide Hydrogen Evolution Reaction Ph-universal Ru-pt Nanoparticle
DOI10.1002/adfm.202411081
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:001296778700001
PublisherWILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85201801899
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Document TypeJournal article
CollectionFaculty of Science and Technology
INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
DEPARTMENT OF PHYSICS AND CHEMISTRY
Corresponding AuthorPeng, Jing; Pan, Hui; Cheng, Hui Ming
Affiliation1.Institute of Applied Physics and Materials Engineering, University of Macau, 999078, Macao
2.Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China
3.Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China
4.Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, 999078, Macao
5.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING;  Faculty of Science and Technology
Recommended Citation
GB/T 7714
Yang, Junge,Feng, Jinxian,Cao, Youpeng,et al. Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution[J]. Advanced Functional Materials, 2024, 2411081.
APA Yang, Junge., Feng, Jinxian., Cao, Youpeng., Xiao, Yuxuan., Qiao, Lulu., An, Keyu., Yang, Jiao., Peng, Jing., Pan, Hui., & Cheng, Hui Ming (2024). Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution. Advanced Functional Materials, 2411081.
MLA Yang, Junge,et al."Highly Dispersed Ru-Pt Heterogeneous Nanoparticles on Reduced Graphene Oxide for Efficient pH-Universal Hydrogen Evolution".Advanced Functional Materials (2024):2411081.
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