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Highly-Entangled Hydrogel Electrolyte for Fast Charging/Discharging Properties in Aqueous Zinc Ion Batteries
Shen, Zhaoxi1; Liu, Yu2; Li, Zhongheng2; Tang, Ziqing3; Pu, Jun4; Luo, Lei2; Ji, Yu2; Xie, Junpeng5; Shu, Zheng2; Yao, Yagang4; Zhang, Ning1; Hong, Guo5
2024-07
Source PublicationAdvanced Functional Materials
ISSN1616-301X
Pages2406620
Abstract

Aqueous zinc ion batteries coupling with conventional hydrogel electrolyte have the advantages of high safety, low cost, and simple manufacturing process while they are difficult for fast charging/discharging application scenarios due to the sluggish kinetics. Herein, a new strategy is developed for synthesizing a highly-entangled polyacrylamide (HE-PAM) hydrogel electrolyte to dramatically enhance the ion transportation and mechanical stability. The developed hydrogel electrolyte has lower ionic resistance and a strong elastic modulus. After being assembled into Zn/MnO2 batteries, the HE-PAM hydrogel electrolyte exhibits excellent cycling stability and high-rate capability under high current densities. Specifically, the Zn//HE-PAM//MnO2 battery can resist the highest current of 35 Ag-1, which outperforms previously reported works. Moreover, the HE-PAM hydrogel electrolyte can also support the fast charging/discharging in proton ion batteries with a high capacity retention rate of 50% under 50 Ag-1. This progress on hydrogel electrolytes can boost the development of quasi-solid-state batteries in the fast charging/discharging aspect.

KeywordFast Charging/discharging Highly-entangled Polyacrylamide Hydrogel Electrolyte Proton Ion Batteries Zn/mno2 Batteries
DOI10.1002/adfm.202406620
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:001263080700001
PublisherWILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85197874614
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorZhang, Ning; Hong, Guo
Affiliation1.College of Chemistry and Materials Science, Key Laboratory of Analytical Science and Technology of Hebei Province, Institute of Life Science and Green Development, Hebei University, Baoding, 071002, China
2.Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, 999078, Macao
3.Wenzhou Institute, University of Chinese Academy of Sciences, Wenzhou, 352001, China
4.National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, Collaborative Innovation Center of Advanced Microstructures, Nanjing University
5.Department of Materials Science and Engineering & Centre of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, Kowloon, 999077, Hong Kong
Recommended Citation
GB/T 7714
Shen, Zhaoxi,Liu, Yu,Li, Zhongheng,et al. Highly-Entangled Hydrogel Electrolyte for Fast Charging/Discharging Properties in Aqueous Zinc Ion Batteries[J]. Advanced Functional Materials, 2024, 2406620.
APA Shen, Zhaoxi., Liu, Yu., Li, Zhongheng., Tang, Ziqing., Pu, Jun., Luo, Lei., Ji, Yu., Xie, Junpeng., Shu, Zheng., Yao, Yagang., Zhang, Ning., & Hong, Guo (2024). Highly-Entangled Hydrogel Electrolyte for Fast Charging/Discharging Properties in Aqueous Zinc Ion Batteries. Advanced Functional Materials, 2406620.
MLA Shen, Zhaoxi,et al."Highly-Entangled Hydrogel Electrolyte for Fast Charging/Discharging Properties in Aqueous Zinc Ion Batteries".Advanced Functional Materials (2024):2406620.
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