Electrocatalytic C−N Couplings at Cathode and Anode

doi:10.1002/aenm.202303820

UM > INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING

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	Electrocatalytic C−N Couplings at Cathode and Anode
	Chen, Dawei 1,2; Liu, Jiani 1,3; Shen, Jingjun 4; Zhang, Yiqiong 1,3; Shao, Huaiyu4 ; Chen, Chen 1; Wang, Shuangyin 1
	2024-07-26
Source Publication	Advanced Energy Materials
ISSN	1614-6832
Volume	14 Issue:28
Abstract	Electrocatalytic C−N couplings are promising alternatives to construct C−N bonds and to synthesize vital chemicals, including amine, amide, amino acid, oxime, imine, and nitrile, under ambient conditions. In recent years, the electrocatalytic C−N coupling has attracted a wide range of research interest and has achieved considerable developments. Here, the electrocatalytic C−N coupling is systematically reviewed aiming at reductive cathode and oxidative anode. In the cathodic part, the electrocatalytic coupling reaction systems, the corresponding design principles of electrocatalysts for different reaction systems, the mechanism studies from experimental and theoretical aspects, and the application-oriented electrocatalytic devices for electrocatalytic C−N couplings are summarized. Anodic C−N coupling offers a potential approach to replace the conventional energy-demand synthesis protocols, and is an indispensable part of the green and controllable construction of unsaturated C = N and C≡N bonds. According to the principle that electron transfer is the crucial point in anodic C−N coupling, the anodic coupling reactions are sorted out based on the direct and the indirect C−N coupling paths, respectively. Finally, the challenges and outlooks in this field are proposed. Electrocatalytic C−N coupling is an appealing research topic in electrochemistry and possesses infinite possibilities in the future.
Keyword	anodic coupling cathodic coupling C−N coupling electrocatalytic coupling system reaction mechanism
DOI	10.1002/aenm.202303820
URL	View the original
Language	英語English
Scopus ID	2-s2.0-85185470292
Fulltext Access	View Full-Text via DOI View Full-Text via Web of Science View Full-Text via Scopus
Citation statistics
Document Type	Journal article
Collection	INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Affiliation	1.State Key Laboratory of Chemo/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China 2.College of Material Science and Engineering, Qingdao University of Science and Technology, Qingdao, Zhengzhou Road 53, 266042, China 3.College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, 410082, China 4.Guangdong-Hong Kong-Macau Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade SAR, 999078, Macao
Recommended Citation GB/T 7714	Chen, Dawei,Liu, Jiani,Shen, Jingjun,et al. Electrocatalytic C−N Couplings at Cathode and Anode[J]. Advanced Energy Materials, 2024, 14(28).
APA	Chen, Dawei., Liu, Jiani., Shen, Jingjun., Zhang, Yiqiong., Shao, Huaiyu., Chen, Chen., & Wang, Shuangyin (2024). Electrocatalytic C−N Couplings at Cathode and Anode. Advanced Energy Materials, 14(28).
MLA	Chen, Dawei,et al."Electrocatalytic C−N Couplings at Cathode and Anode".Advanced Energy Materials 14.28(2024).

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