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Bi-Functional Chelating Ligand Enables Ultra-Stable Blue Emissive CsPbBr3 Nanoplatelets Film
Lin, Hao1; Gao, Pei Li1; Dong, Jia Yi1; Li, Jie Lei1; Lian, Zhen Dong1; Xu, Jin Cheng1; Ng, Kar Wei1; Chen, Shi1; Su, Shi Chen2; Liu, Hong-Chao1; Wu, Zhao Xin3; Wang, Shuang Peng1
2024
Source PublicationAdvanced Optical Materials
ISSN2195-1071
Pages2400214
Abstract

Quantum-confined perovskite CsPbBr Nanoplatelets (NPLs) have recently emerged as promising blue-emitting materials for perovskite light-emitting diodes (PeLEDs). Yet, their susceptibility to optical instability in solid films under ambient conditions poses a significant hindrance. This study introduces a novel chelating strategy that utilizes metal manganese ions and multidentate ligands, markedly improving the structural stability, and emission efficiency of NPLs. The approach involves adding Diethylenetriaminepentaacetic acid (DTPA) to the perovskite precursor solution, which allows for strong coordination to surface [PbBr] octahedrons via its multiple chelation sites. Ensuing metal manganese ion integration during the purification phase addresses Pb and Br site vacancies, culminating in near-perfect octahedral structures with significantly fewer vacancies. These metal manganese ions are then further immobilized on the NPLs surface by the chelating effect of unbound DTPA functional groups. The resultant CsPbBr NPLs films demonstrate an impressive PLQY of 66%, showcasing remarkable air stability with consistent blue emission for up to 5 days. The CsPbBr NPLs-based PeLEDs show electroluminescence at 460 nm with a current efficiency of 1.07 cd A and a maximum luminance of 220 cd m. The proposed chelating strategy positions perovskite NPLs as an extremely promising prospect in future applications of high-definition displays and high-quality lighting.

KeywordBlue Emission Chelating Effect Cspbbr3 Nanoplatelets Perovskite Light-emitting Diodes Structural Stability
DOI10.1002/adom.202400214
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaMaterials Science ; Optics
WOS SubjectMaterials Science, Multidisciplinary ; Optics
WOS IDWOS:001199931400001
PublisherWILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85189973573
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorLiu, Hong-Chao; Wu, Zhao Xin; Wang, Shuang Peng
Affiliation1.Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, SAR, 999078, Macao
2.School of Semiconductor Science and Technology, South China Normal University, Foshan, 528000, China
3.Key Laboratory for Physical Electronics and Devices of the Ministry of Education & Shaanxi Key Lab of Information Photonic Technique, School of Electronic Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Lin, Hao,Gao, Pei Li,Dong, Jia Yi,et al. Bi-Functional Chelating Ligand Enables Ultra-Stable Blue Emissive CsPbBr3 Nanoplatelets Film[J]. Advanced Optical Materials, 2024, 2400214.
APA Lin, Hao., Gao, Pei Li., Dong, Jia Yi., Li, Jie Lei., Lian, Zhen Dong., Xu, Jin Cheng., Ng, Kar Wei., Chen, Shi., Su, Shi Chen., Liu, Hong-Chao., Wu, Zhao Xin., & Wang, Shuang Peng (2024). Bi-Functional Chelating Ligand Enables Ultra-Stable Blue Emissive CsPbBr3 Nanoplatelets Film. Advanced Optical Materials, 2400214.
MLA Lin, Hao,et al."Bi-Functional Chelating Ligand Enables Ultra-Stable Blue Emissive CsPbBr3 Nanoplatelets Film".Advanced Optical Materials (2024):2400214.
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