Residential College | false |
Status | 已發表Published |
Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries | |
Xiao, Fangyuan1,2; Wang, Xiaoke1,2; Sun, Kaitong1; Zhao, Qian1; Han, Cuiping2; Li, Hai Feng1 | |
2024-06-01 | |
Source Publication | Chemical Engineering Journal |
ISSN | 1385-8947 |
Volume | 489Pages:151111 |
Abstract | Corrosion and the formation of by-products resulting from parasitic side reactions, as well as random dendrite growth, pose significant challenges for aqueous zinc-ion batteries (AZIBs). In this study, phytate ammonium is introduced into the traditional dilute Zinc sulfate electrolyte as a multi-functional additive. Leveraging the inherent zincophilic nature of the phytic anion, a protective layer is formed on the surface of the zinc anode. This layer can effectively manipulate the deposition process, mitigate parasitic reactions, and reduce the accumulation of detrimental by-products. Additionally, the competitive deposition between dissociated ammonium ions and Zn promotes uniform deposition, thereby alleviating dendrite growth. Consequently, the modified electrolyte with a lower volume addition exhibits superior performance. The zinc symmetric battery demonstrates much more reversible plating/stripping, sustaining over 2000 h at 5 mA cm and 1 mA h cm. A high average deposition/stripping efficiency of 99.83 % is achieved, indicating the significant boosting effect and practical potential of our strategy for high-performance aqueous zinc-ion batteries. |
Keyword | Zinc-ion Battery Anode Electrolyte Design Effective Additive |
DOI | 10.1016/j.cej.2024.151111 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Engineering |
WOS Subject | Engineering, Environmental ; Engineering, Chemical |
WOS ID | WOS:001285784000001 |
Publisher | ELSEVIER SCIENCE SAPO BOX 564, 1001 LAUSANNE, SWITZERLAND |
Scopus ID | 2-s2.0-85190246381 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Han, Cuiping; Li, Hai Feng |
Affiliation | 1.Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macao SAR, 999078, China 2.Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong, 518055, China |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Xiao, Fangyuan,Wang, Xiaoke,Sun, Kaitong,et al. Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries[J]. Chemical Engineering Journal, 2024, 489, 151111. |
APA | Xiao, Fangyuan., Wang, Xiaoke., Sun, Kaitong., Zhao, Qian., Han, Cuiping., & Li, Hai Feng (2024). Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries. Chemical Engineering Journal, 489, 151111. |
MLA | Xiao, Fangyuan,et al."Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries".Chemical Engineering Journal 489(2024):151111. |
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