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Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries
Xiao, Fangyuan1,2; Wang, Xiaoke1,2; Sun, Kaitong1; Zhao, Qian1; Han, Cuiping2; Li, Hai Feng1
2024-06-01
Source PublicationChemical Engineering Journal
ISSN1385-8947
Volume489Pages:151111
Abstract

Corrosion and the formation of by-products resulting from parasitic side reactions, as well as random dendrite growth, pose significant challenges for aqueous zinc-ion batteries (AZIBs). In this study, phytate ammonium is introduced into the traditional dilute Zinc sulfate electrolyte as a multi-functional additive. Leveraging the inherent zincophilic nature of the phytic anion, a protective layer is formed on the surface of the zinc anode. This layer can effectively manipulate the deposition process, mitigate parasitic reactions, and reduce the accumulation of detrimental by-products. Additionally, the competitive deposition between dissociated ammonium ions and Zn promotes uniform deposition, thereby alleviating dendrite growth. Consequently, the modified electrolyte with a lower volume addition exhibits superior performance. The zinc symmetric battery demonstrates much more reversible plating/stripping, sustaining over 2000 h at 5 mA cm and 1 mA h cm. A high average deposition/stripping efficiency of 99.83 % is achieved, indicating the significant boosting effect and practical potential of our strategy for high-performance aqueous zinc-ion batteries.

KeywordZinc-ion Battery Anode Electrolyte Design Effective Additive
DOI10.1016/j.cej.2024.151111
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaEngineering
WOS SubjectEngineering, Environmental ; Engineering, Chemical
WOS IDWOS:001285784000001
PublisherELSEVIER SCIENCE SAPO BOX 564, 1001 LAUSANNE, SWITZERLAND
Scopus ID2-s2.0-85190246381
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorHan, Cuiping; Li, Hai Feng
Affiliation1.Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macao SAR, 999078, China
2.Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, Guangdong, 518055, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Xiao, Fangyuan,Wang, Xiaoke,Sun, Kaitong,et al. Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries[J]. Chemical Engineering Journal, 2024, 489, 151111.
APA Xiao, Fangyuan., Wang, Xiaoke., Sun, Kaitong., Zhao, Qian., Han, Cuiping., & Li, Hai Feng (2024). Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries. Chemical Engineering Journal, 489, 151111.
MLA Xiao, Fangyuan,et al."Zincophilic armor: Phytate ammonium as a multifunctional additive for enhanced performance in aqueous zinc-ion batteries".Chemical Engineering Journal 489(2024):151111.
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