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Tunable Adhesion for All-Dry Transfer of 2D Materials Enabled by the Freezing of Transfer Medium
Chen, Sensheng1,2,3; Chen, Ge3; Zhao, Yixuan3,4; Bu, Saiyu2; Hu, Zhaoning2,3; Mao, Boyang5; Wu, Haotian2; Liao, Junhao3,4,6; Li, Fangfang3,6; Zhou, Chaofan2,3; Guo, Bingbing3; Liu, Wenlin3,4; Zhu, Yaqi2,3,7; Lu, Qi3,8; Hu, Jingyi6; Shang, Mingpeng3,4,6; Shi, Zhuofeng2,3,7; Yu, Beiming2; Zhang, Xiaodong7; Zhao, Zhenxin1; Jia, Kaicheng3; Zhang, Yanfeng2; Sun, Pengzhan9; Liu, Zhongfan3,4; Lin, Li2,3,4,6; Wang, Xiaomin1
2024-04-11
Source PublicationAdvanced Materials
ISSN0935-9648
Volume36Issue:15Pages:2308950
Abstract

The real applications of chemical vapor deposition (CVD)-grown graphene films require the reliable techniques for transferring graphene from growth substrates onto application-specific substrates. The transfer approaches that avoid the use of organic solvents, etchants, and strong bases are compatible with industrial batch processing, in which graphene transfer should be conducted by dry exfoliation and lamination. However, all-dry transfer of graphene remains unachievable owing to the difficulty in precisely controlling interfacial adhesion to enable the crack- and contamination-free transfer. Herein, through controllable crosslinking of transfer medium polymer, the adhesion is successfully tuned between the polymer and graphene for all-dry transfer of graphene wafers. Stronger adhesion enables crack-free peeling of the graphene from growth substrates, while reduced adhesion facilitates the exfoliation of polymer from graphene surface leaving an ultraclean surface. This work provides an industrially compatible approach for transferring 2D materials, key for their future applications, and offers a route for tuning the interfacial adhesion that would allow for the transfer-enabled fabrication of van der Waals heterostructures.

KeywordCvd Graphene Films Dry Transfer Graphene Transfer Graphene Wafers Ultraclean Surface
DOI10.1002/adma.202308950
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:001157650500001
PublisherWILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Scopus ID2-s2.0-85184235126
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorBu, Saiyu; Liu, Zhongfan; Lin, Li; Wang, Xiaomin
Affiliation1.School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, 030002, China
2.School of Materials Science and Engineering, Peking University, Beijing, 100871, China
3.Technology Innovation Center of Graphene Metrology and Standardization for State Market Regulation, Beijing Graphene Institute, Beijing, 100095, China
4.Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China
5.Department of Engineering, University of Cambridge, Cambridge, CB3 0FA, United Kingdom
6.Academy for Advanced Interdisciplinary Studies, Peking University, Beijing, 100871, China
7.College of Chemical Science and Engineering, Qingdao University, Qingdao, 266071, China
8.College of Science, China University of Petroleum, Beijing, 102249, China
9.Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, SAR, 999078, Macao
Recommended Citation
GB/T 7714
Chen, Sensheng,Chen, Ge,Zhao, Yixuan,et al. Tunable Adhesion for All-Dry Transfer of 2D Materials Enabled by the Freezing of Transfer Medium[J]. Advanced Materials, 2024, 36(15), 2308950.
APA Chen, Sensheng., Chen, Ge., Zhao, Yixuan., Bu, Saiyu., Hu, Zhaoning., Mao, Boyang., Wu, Haotian., Liao, Junhao., Li, Fangfang., Zhou, Chaofan., Guo, Bingbing., Liu, Wenlin., Zhu, Yaqi., Lu, Qi., Hu, Jingyi., Shang, Mingpeng., Shi, Zhuofeng., Yu, Beiming., Zhang, Xiaodong., ...& Wang, Xiaomin (2024). Tunable Adhesion for All-Dry Transfer of 2D Materials Enabled by the Freezing of Transfer Medium. Advanced Materials, 36(15), 2308950.
MLA Chen, Sensheng,et al."Tunable Adhesion for All-Dry Transfer of 2D Materials Enabled by the Freezing of Transfer Medium".Advanced Materials 36.15(2024):2308950.
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