UM
Residential Collegefalse
Status已發表Published
Unveiling the Role of Charge Dilution and Anionic Chemistry in Enabling High-Rate p-Type Polymer Cathodes for Dual-Ion Batteries
Zhong, Linfeng1; Zhang, Yang1; Li, Jing2; Fang, Long1; Liu, Cong1; Wang, Xiaotong1; Zhang, Zishou1; Yu, Dingshan1,3
2023-09-26
Source PublicationACS nano
ISSN1936-086X
Volume17Issue:18Pages:18190 - 18199
Abstract

Herein, we introduce a p-type redox conjugated covalent organic polymer (p-PNZ) as a universal and high-rate cathode for diverse dual-ion batteries. By constructing an n-type redox counterpart (n-PNZ) with an analogous reticular structure and redox-site composition, we also attain a comparative platform to probe how the redox-site nature and counterion chemistry affect the rate performance of polymer cathodes. It is disclosed that the charge dilution in p-type redox sites and bulky anions engenders their weak interaction and rapid anion diffusion in electrodes, while the trivial interaction of the solvent with anions facilitates anion desolvation and interfacial charge transfer. Thus, p-PNZ possesses rapid surface-controlled redox kinetics with a high anion diffusion coefficient regardless of its inferior porosity and conductivity relative to n-PNZ. Along with a long cycle life of over 50000 cycles, the p-PNZ-engaged Zn-based dual-ion battery with a dilute electrolyte delivers nearly constant capacities of ∼149 mAh g-1 at various rates of ≤10 A g-1─such an unusual rate capability has rarely been observed previously─and retains ∼99 mAh g-1 at 40 A g-1, surpassing the n-PNZ counterpart and most existing p-type organic cathodes. The p-PNZ cathode can also be applied to build high-rate Li-based batteries, signifying its universality, while the "ready-to-charge" character of p-PNZ enables anode-free dual-ion batteries with a high-rate capability and long lifespan.

KeywordAnode-free Batteries Covalent Organic Polymers Dual-ion Batteries Organic Electrodes Polymer Electrodes
DOI10.1021/acsnano.3c05077
URLView the original
Language英語English
Scopus ID2-s2.0-85172425085
Fulltext Access
Citation statistics
Document TypeJournal article
Affiliation1.Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Key Laboratory of High-Performance Polymer-based Composites of Guangdong Province, School of Chemistry, Sun Yat-sen University, Guangzhou, 510006, China
2.Guangdong-Hong Kong-Macau Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices, Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Avenida da Universidade, China
3.GBRCE for Functional Molecular Engineering, Sun Yat-sen University, Guangzhou, 510006, China
Recommended Citation
GB/T 7714
Zhong, Linfeng,Zhang, Yang,Li, Jing,et al. Unveiling the Role of Charge Dilution and Anionic Chemistry in Enabling High-Rate p-Type Polymer Cathodes for Dual-Ion Batteries[J]. ACS nano, 2023, 17(18), 18190 - 18199.
APA Zhong, Linfeng., Zhang, Yang., Li, Jing., Fang, Long., Liu, Cong., Wang, Xiaotong., Zhang, Zishou., & Yu, Dingshan (2023). Unveiling the Role of Charge Dilution and Anionic Chemistry in Enabling High-Rate p-Type Polymer Cathodes for Dual-Ion Batteries. ACS nano, 17(18), 18190 - 18199.
MLA Zhong, Linfeng,et al."Unveiling the Role of Charge Dilution and Anionic Chemistry in Enabling High-Rate p-Type Polymer Cathodes for Dual-Ion Batteries".ACS nano 17.18(2023):18190 - 18199.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhong, Linfeng]'s Articles
[Zhang, Yang]'s Articles
[Li, Jing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhong, Linfeng]'s Articles
[Zhang, Yang]'s Articles
[Li, Jing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhong, Linfeng]'s Articles
[Zhang, Yang]'s Articles
[Li, Jing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.