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High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes
Luo,Lei1; Liu,Yu1; Shen,Zhaoxi1; Wen,Zhaorui1; Chen,Shi1; Hong,Guo2
2023-06-08
Source PublicationACS Applied Materials and Interfaces
ISSN1944-8244
Volume15Issue:24Pages:29032-29041
Abstract

Because of the high safety and environmental friendliness, aqueous zinc-ion batteries have gained a lot of attention in recent years. Prussian blue and its analogues are regarded as a promising cathode material of zinc-ion batteries. Manganese hexacyanoferrate is appropriate among them due to its high operating voltage, large capacity, and cheap price. However, the poor cycling stability of manganese hexacyanoferrate, mainly caused by transition metal dissolution, side reaction, and phase transition, greatly restricts its practical application. In this work, gelatin is used to limit the content of free water in the electrolyte, thus reducing the dissolution effect of transition metal manganese. The introduction of gelatin improves the durability of the Zn anode as well. The optimized MnHCF/gel-0.3/Zn battery displays a high reversible capacity (120 mAh·g at 0.1 A·g), an excellent rate performance (42.7 mAh·g at 2 A·g), and a good capacity retention (65% at 0.5 A·g after 1000 cycles).

KeywordGel Electrolyte Gelatin High Voltage Manganese Hexacyanoferrate Zinc-ion Battery
DOI10.1021/acsami.3c00905
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:001002593800001
PublisherAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036
Scopus ID2-s2.0-85163765005
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding AuthorHong,Guo
Affiliation1.Institute of Applied Physics and Materials Engineering,University of Macau,Taipa,Avenida da Universidade, SAR,999078,Macao
2.Department of Materials Science and Engineering & Center of Super-Diamond and Advanced Films,College of Engineering,City University of Hong Kong,Kowloon,83 Tat Chee Avenue, SAR,999077,Hong Kong
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Luo,Lei,Liu,Yu,Shen,Zhaoxi,et al. High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes[J]. ACS Applied Materials and Interfaces, 2023, 15(24), 29032-29041.
APA Luo,Lei., Liu,Yu., Shen,Zhaoxi., Wen,Zhaorui., Chen,Shi., & Hong,Guo (2023). High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes. ACS Applied Materials and Interfaces, 15(24), 29032-29041.
MLA Luo,Lei,et al."High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes".ACS Applied Materials and Interfaces 15.24(2023):29032-29041.
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