Residential College | false |
Status | 已發表Published |
High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes | |
Luo,Lei1; Liu,Yu1; Shen,Zhaoxi1; Wen,Zhaorui1; Chen,Shi1![]() ![]() | |
2023-06-08 | |
Source Publication | ACS Applied Materials and Interfaces
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ISSN | 1944-8244 |
Volume | 15Issue:24Pages:29032-29041 |
Abstract | Because of the high safety and environmental friendliness, aqueous zinc-ion batteries have gained a lot of attention in recent years. Prussian blue and its analogues are regarded as a promising cathode material of zinc-ion batteries. Manganese hexacyanoferrate is appropriate among them due to its high operating voltage, large capacity, and cheap price. However, the poor cycling stability of manganese hexacyanoferrate, mainly caused by transition metal dissolution, side reaction, and phase transition, greatly restricts its practical application. In this work, gelatin is used to limit the content of free water in the electrolyte, thus reducing the dissolution effect of transition metal manganese. The introduction of gelatin improves the durability of the Zn anode as well. The optimized MnHCF/gel-0.3/Zn battery displays a high reversible capacity (120 mAh·g at 0.1 A·g), an excellent rate performance (42.7 mAh·g at 2 A·g), and a good capacity retention (65% at 0.5 A·g after 1000 cycles). |
Keyword | Gel Electrolyte Gelatin High Voltage Manganese Hexacyanoferrate Zinc-ion Battery |
DOI | 10.1021/acsami.3c00905 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Science & Technology - Other Topics ; Materials Science |
WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:001002593800001 |
Publisher | AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 |
Scopus ID | 2-s2.0-85163765005 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Hong,Guo |
Affiliation | 1.Institute of Applied Physics and Materials Engineering,University of Macau,Taipa,Avenida da Universidade, SAR,999078,Macao 2.Department of Materials Science and Engineering & Center of Super-Diamond and Advanced Films,College of Engineering,City University of Hong Kong,Kowloon,83 Tat Chee Avenue, SAR,999077,Hong Kong |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Luo,Lei,Liu,Yu,Shen,Zhaoxi,et al. High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes[J]. ACS Applied Materials and Interfaces, 2023, 15(24), 29032-29041. |
APA | Luo,Lei., Liu,Yu., Shen,Zhaoxi., Wen,Zhaorui., Chen,Shi., & Hong,Guo (2023). High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes. ACS Applied Materials and Interfaces, 15(24), 29032-29041. |
MLA | Luo,Lei,et al."High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes".ACS Applied Materials and Interfaces 15.24(2023):29032-29041. |
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