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Tailoring the growth of iron hexacyanoferrates for high-performance cathode of sodium-ion batteries
Xiang, Jingjing1; Hao, Youchen2; Gao, Yuting2; Ji, Lei3; Wang, Li3; Sun, Guoxing4; Tang, Yuxin5; Zhu, Yaofeng1; Jiang, Yinzhu2,3
2023-02-13
Source PublicationJournal of Alloys and Compounds
ISSN0925-8388
Volume946Pages:169284
Abstract

Iron hexacyanoferrate (FeHCF) is regarded as a promising cathode material of sodium-ion batteries (SIBs) due to the merits of easy preparation, low cost and three-dimensional open framework. However, the practical application of FeHCF is highly restricted by the intrinsic [Fe(CN)] vacancy and coordinated water as well as nanoscale particles. Herein, sodium citrate is introduced to mediate the drawbacks of FeHCF, resulting in microscale particles with less water content. Accordingly, the modified sample, FeHCF-3, achieved the performance of 92 mA h g at 100 mA g and 80 % capacity retention after 300 cycles. Furthermore, an optimal iron hexacyanoferrate (FeHCF-H-2) with high-salt-concentration preparation is designed and performs a good reversibility of 96 mA h g after 700 cycles at 100 mA g. Such strategy may drive the application of high-tap, low-defect and stable cathode for SIBs.

KeywordGood Reversibility Iron Hexacyanoferrate Low Vacancy Sodium Citrate Sodium-ion Batteries
DOI10.1016/j.jallcom.2023.169284
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaChemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000948409200001
PublisherELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Scopus ID2-s2.0-85148673355
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Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Co-First AuthorXiang, Jingjing
Corresponding AuthorZhu, Yaofeng; Jiang, Yinzhu
Affiliation1.School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018, China
2.School of Materials Science and Engineering, ZJU-Hangzhou Global Scientific and Technological Innovation Centre, Zhejiang University, Hangzhou, 310027, China
3.State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou, 014030, China
4.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau SAR, China
5.College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
Recommended Citation
GB/T 7714
Xiang, Jingjing,Hao, Youchen,Gao, Yuting,et al. Tailoring the growth of iron hexacyanoferrates for high-performance cathode of sodium-ion batteries[J]. Journal of Alloys and Compounds, 2023, 946, 169284.
APA Xiang, Jingjing., Hao, Youchen., Gao, Yuting., Ji, Lei., Wang, Li., Sun, Guoxing., Tang, Yuxin., Zhu, Yaofeng., & Jiang, Yinzhu (2023). Tailoring the growth of iron hexacyanoferrates for high-performance cathode of sodium-ion batteries. Journal of Alloys and Compounds, 946, 169284.
MLA Xiang, Jingjing,et al."Tailoring the growth of iron hexacyanoferrates for high-performance cathode of sodium-ion batteries".Journal of Alloys and Compounds 946(2023):169284.
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