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Facile Hydrogels of AIEgens Applied as Reusable Sensors for In Situ and Early Warning of Metallic Corrosion
Honglei Guo1; Canjie Zhu1,2; Zihao Yuan1; Guang Huang1,3; Huansen Liang1; Chenxi Xiong1; Zhiyuan Feng1; Qiang Wei4; Guozhe Meng1
2023-01-31
Source PublicationACS Applied Materials & Interfaces
ISSN1944-8244
Volume15Issue:6Pages:8530-8536
Abstract

Early detection of metallic corrosion is one considerable method to reduce imperceptible disasters nowadays. Fluorescent coatings with high sensitivity and long lifetimes for use in the early detection of metallic corrosion are in high demand, but they are presently difficult to prepare. Inspired by the chameleon’s skin, which is capable of switching its color in different atmospheres sensitively and reversibly, we proposed herein a facile and universal all-in-one strategy of combining the fluorescent sensitivity and dynamic hydrogen bonds in a hydrogel to develop a reusable corrosion detection tape to cover metal surfaces. The fluorescent hydrogel tape was constructed using free radical copolymerization of monomers [hydroxyethyl methylacrylate (HEMA) and tetraphenylethene derivatives (TPEPy)]. Due to the aggregation-induced emission (AIE) behavior of TPEPy, the poly(HEMA-co-TPEPy) hydrogel is capable of monitoring the traces of corrosion via the release of ferric ions with a concentration as low as 10 M. Moreover, due to the dynamic hydrogen bonds of hydroxyethyl groups in hydrogel networks, the fluorescent hydrogel tape exhibited good adhesion and well reusability for over 10 applications to effectively warn against early corrosion of stainless steel. This non-destructive and reversible method of early corrosion detection can provide valuable signals when maintenance is needed before the metal suffers serious damage.

KeywordHydrogel Early Warning Metallic Corrosion Aiegens Reusability
DOI10.1021/acsami.2c21798
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
PublisherAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036
Scopus ID2-s2.0-85147203682
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Document TypeJournal article
CollectionFaculty of Science and Technology
Corresponding AuthorHonglei Guo; Qiang Wei; Guozhe Meng
Affiliation1.School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, China
2.School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510006, China
3.Faculty of Science and Technology, University of Macau, Taipa, 999078, Macao
4.Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo, 315201, China
Recommended Citation
GB/T 7714
Honglei Guo,Canjie Zhu,Zihao Yuan,et al. Facile Hydrogels of AIEgens Applied as Reusable Sensors for In Situ and Early Warning of Metallic Corrosion[J]. ACS Applied Materials & Interfaces, 2023, 15(6), 8530-8536.
APA Honglei Guo., Canjie Zhu., Zihao Yuan., Guang Huang., Huansen Liang., Chenxi Xiong., Zhiyuan Feng., Qiang Wei., & Guozhe Meng (2023). Facile Hydrogels of AIEgens Applied as Reusable Sensors for In Situ and Early Warning of Metallic Corrosion. ACS Applied Materials & Interfaces, 15(6), 8530-8536.
MLA Honglei Guo,et al."Facile Hydrogels of AIEgens Applied as Reusable Sensors for In Situ and Early Warning of Metallic Corrosion".ACS Applied Materials & Interfaces 15.6(2023):8530-8536.
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