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A comprehensive review on the ferroelectric orthochromates: Synthesis, property, and application
Zhu, Yinghao1; Sun, Kaitong1,3; Wu, Si1,2; Zhou, Pengfei1; Fu, Ying1; Xia, Junchao1; Li, Hai Feng1
Source PublicationCoordination Chemistry Reviews
ISSN0010-8545
2023-01-15
Abstract

Multiferroics represent a class of advanced materials for promising applications and stand at the forefront of modern science for the special feature possessing both charge polar and magnetic order. Previous studies indicate that the family of RECrO (RE = rare earth) compounds is likely another rare candidate system holding both ferroelectricity and magnetism. However, many issues remain unsolved, casting hot disputes about whether RECrO is multiferroic or not. For example, an incompatibility exists between reported structural models and observed ferroelectric behaviors, and it is not easy to determine the spin canting degree. To address these questions, one key step is to grow single crystals because they can provide more reliable information than other forms of matter do. In this review, the parent and doped ferroelectric YCrO compounds are comprehensively reviewed based on scientific and patent literatures from 1954 to 2022. The materials syntheses with different methods, including poly-, nano-, and single-crystalline samples and thin films, are summarized. The structural, magnetic, ferroelectric and dielectric, optical, and chemical-pressure (on Y and Cr sites by doping) dependent chemical and physical properties and the corresponding phase diagrams, are discussed. Diverse (potential) applications, including anti-corrosion, magnetohydrodynamic electrode, catalyst, negative-temperature-coefficient thermistor, magnetic refrigeration, protective coating, and solid oxide fuel cell, are present. To conclude, we summarize general results, reached consensuses, and existing controversies of the past nearly 69 years of intensive studies and highlight future research opportunities and emerging challenges to address existing issues.

KeywordApplication Chemical Pressure Ferroelectricity Magnetism Multiferroics Optical Orthochromates Phase Diagram Structure Synthesis
Language英語English
DOI10.1016/j.ccr.2022.214873
URLView the original
Volume475
Pages214873
WOS IDWOS:000903825300001
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
Indexed BySCIE
Scopus ID2-s2.0-85140599825
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Document TypeReview article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Co-First AuthorZhu, Yinghao
Corresponding AuthorLi, Hai Feng
Affiliation1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macao SAR, 999078, China
2.School of Physical Science and Technology, Ningbo University, Ningbo, 315211, China
3.Guangdong–Hong Kong–Macao Joint Laboratory for Neutron Scattering Science and Technology, DongGuan, No. 1. Zhongziyuan Road, Dalang, 523803, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Zhu, Yinghao,Sun, Kaitong,Wu, Si,et al. A comprehensive review on the ferroelectric orthochromates: Synthesis, property, and application[J]. Coordination Chemistry Reviews, 2023, 475, 214873.
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