Residential College | false |
Status | 已發表Published |
Two-Photon Optical Properties in Individual Organic-Inorganic Perovskite Microplates | |
Qi Wei1; Bin Du1; Bo Wu2; Jia Guo1; Ming jie Li2; Jianhui Fu2; Zhipeng Zhang1; Jianwei Yu1; Tianyu Hou1; Guichuan Xing3; Tze Chien Sum2; Wei Huang1 | |
2017-12-15 | |
Source Publication | Advanced Optical Materials |
ISSN | 2195-1071 |
Volume | 5Issue:24 |
Abstract | Metal-halide perovskites are recently extensively investigated as light absorbing material in solar cells. The outstanding optoelectronic properties and tunable light emission of the perovskites also make them promising candidates for light emitting diodes and lasers. However, understanding the relevant mechanisms and processes of the dependence of perovskite light emission on temperature and crystal size is still challenging. Herein, the CH3NH3PbBr3 monocrystals of different sizes are uniformly excited by two-photon absorption at 800 nm (100 fs, 1 KHz). In contrast to the reported relative large exciton binding energy (approximate to 76 meV) and spectrum clearly resolved excitonic absorption, the light emission origin in CH3NH3PbBr3 microcrystals at room temperature is unambiguously determined to be dominated by free electron-hole bimolecular recombination. The coherent light emission threshold of CH3NH3PbBr3 microcrystal increases with temperature, which is closely related to the temperature induced transition from exciton gas to free charge carriers. In addition, the coherent light emission threshold is found to decrease with the microcrystal size, which could be well interpreted by the interaction between the optical confinement, defect density, and cavity quantum electrodynamics effect. These results presented here may facilitate the development of perovskite light emitting diodes and lasers. |
Keyword | Amplified Spontaneous Emission Excitons And Free Carriers Microlasers Multiphoton Absorption Perovskites |
DOI | 10.1002/adom.201700809 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Materials Science ; Optics |
WOS Subject | Materials Science, Multidisciplinary ; Optics |
WOS ID | WOS:000418123300013 |
Publisher | WILEY-V C H VERLAG GMBH |
The Source to Article | WOS |
Scopus ID | 2-s2.0-85032902461 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author | Guichuan Xing; Tze Chien Sum; Wei Huang |
Affiliation | 1.Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing, 211816 China 2.Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University (NTU), 21 Nanyang Link, 637371 Singapore, Singapore 3.Institute of Applied Physics and Materials Engineering, University of Macau, Macao SAR, 999078 China |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Qi Wei,Bin Du,Bo Wu,et al. Two-Photon Optical Properties in Individual Organic-Inorganic Perovskite Microplates[J]. Advanced Optical Materials, 2017, 5(24). |
APA | Qi Wei., Bin Du., Bo Wu., Jia Guo., Ming jie Li., Jianhui Fu., Zhipeng Zhang., Jianwei Yu., Tianyu Hou., Guichuan Xing., Tze Chien Sum., & Wei Huang (2017). Two-Photon Optical Properties in Individual Organic-Inorganic Perovskite Microplates. Advanced Optical Materials, 5(24). |
MLA | Qi Wei,et al."Two-Photon Optical Properties in Individual Organic-Inorganic Perovskite Microplates".Advanced Optical Materials 5.24(2017). |
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