Achieving long-life Prussian blue analogue cathode for Na-ion batteries via triple-cation lattice substitution and coordinated water capture

Status	已發表Published
	Achieving long-life Prussian blue analogue cathode for Na-ion batteries via triple-cation lattice substitution and coordinated water capture
	Xie, B.; Zuo, P.; Wang, L.; Wang, J.; Huo, H.; He, M.; Shu, J.; Li, H.-F.; Lou, S.; Yin, G.
	2019-04-17
Source Publication	Nano Energy
ISSN	2211-2855
Pages	201-210
Abstract	Prussian blue and its analogues have attracted tremendous interests as cathode materials for sodium ion batteries because of their low cost and high capacity. However, their commercial applications are hindered by low capacity utilization and insufficient cycle life. Here, we report on a MnCoNi-co-doped Prussian blue analogue with high purity and crystallinity by a citrate-assisted controlled crystallization process. Moreover, a novel strategy of in situ capturing for residual coordinated water during sodiation/desodiation process is proposed to achieve a high cyclability by using the aluminium chloride Lewis acid as electrolyte additive. The reversible cubic-rhombohedral phase transition is revealed by in situ X-ray diffraction, ex situ X-ray absorption spectroscopy and transient electrochemical impedance spectroscopy. The MnCoNi-co-doped composite delivers a capacity of 111 mAh g−1 even at 1C and retains a capacity retention of 78.7% after 1500 cycles for sodium ion batteries. This work provides important insights on eliminating the parasitical coordinated water in lattice and modulating the crystallinity to develop high-performance Prussian blue and its analogues.
Keyword	Na-ion batteries triple-cation lattice substitution water capture
URL	View the original
Language	英語English
The Source to Article	PB_Publication
PUB ID	43275
Document Type	Journal article
Collection	University of Macau
Corresponding Author	Zuo, P.; Wang, J.; Shu, J.
Recommended Citation GB/T 7714	Xie, B.,Zuo, P.,Wang, L.,et al. Achieving long-life Prussian blue analogue cathode for Na-ion batteries via triple-cation lattice substitution and coordinated water capture[J]. Nano Energy, 2019, 201-210.
APA	Xie, B.., Zuo, P.., Wang, L.., Wang, J.., Huo, H.., He, M.., Shu, J.., Li, H.-F.., Lou, S.., & Yin, G. (2019). Achieving long-life Prussian blue analogue cathode for Na-ion batteries via triple-cation lattice substitution and coordinated water capture. Nano Energy, 201-210.
MLA	Xie, B.,et al."Achieving long-life Prussian blue analogue cathode for Na-ion batteries via triple-cation lattice substitution and coordinated water capture".Nano Energy (2019):201-210.

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