Residential College | false |
Status | 已發表Published |
High-temperature magnetism and crystallography of a YCrO3 single crystal | |
Zhu, Y. H.1; Wu, S.1; Tu, B.1,2; Jin, S. J.3; Huq, A.4; Persson, J.5; Gao, H. S.1,6; Ouyang, D.6; He, Z. B.2; Yao, D.-X.3; Tang, Z.1; Li, H.-F.1 | |
2020-01-30 | |
Source Publication | Physical Review B |
ISSN | 2469-9969 |
Volume | 101Issue:1Pages:014114 |
Abstract | Magnetization measurements and time-of-flight neutron powder-diffraction studies on the high-temperature (300--980 K) magnetism and crystal structure (321--1200 K) of a pulverized YCrO$_3$ single crystal have been performed. Temperature-dependent inverse magnetic susceptibility coincides with a piecewise linear function with five regimes, with which we fit a Curie-Weiss law and calculate the frustration factor $f$. The fit results indicate a formation of magnetic polarons between 300 and 540 K and a very strong magnetic frustration. By including one factor $\eta$ that represents the degree of spin interactions into the Brillouin function, we can fit well the applied-magnetic-field dependence of magnetization. No structural phase transition was observed from 321 to 1200 K. The average thermal expansions of lattice configurations (\emph{a}, \emph{b}, \emph{c}, and \emph{V}) obey well the Gr$\ddot{\texttt{u}}$neisen approximations with an anomaly appearing around 900 K, implying an isosymmetric structural phase transition, and display an anisotropic character along the crystallographic \emph{a}, \emph{b}, and \emph{c} axes with the incompressibility $K^a_0 > K^c_0 > K^b_0$. It is interesting to find that at 321 K, the local distortion size $\Delta$(O2) $\approx$ 1.96$\Delta$(O1) $\approx$ 4.32$\Delta$(Y) $\approx$ 293.89$\Delta$(Cr). Based on the refined Y-O and Cr-O bond lengths, we deduce the local distortion environments and modes of Y, Cr, O1, and O2 ions. Especially, the Y and O2 ions display obvious atomic displacement and charge subduction, which may shed light on the dielectric property of the YCrO$_3$ compound. Additionally, by comparing Kramers Mn$^{3+}$ with non-Kramers Cr$^{3+}$ ions, it is noted that being a Kramers or non-Kramers ion can strongly affect the local distortion size, whereas, it may not be able to change the detailed distortion mode. |
DOI | 10.1103/PhysRevB.101.014114 |
URL | View the original |
Indexed By | SCIE |
Language | 英語English |
WOS Research Area | Materials Science ; Physics |
WOS Subject | Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
WOS ID | WOS:000510144400001 |
The Source to Article | PB_Publication |
Scopus ID | 2-s2.0-85079555041 |
Fulltext Access | |
Citation statistics | |
Document Type | Journal article |
Collection | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING Institute of Chinese Medical Sciences THE STATE KEY LABORATORY OF QUALITY RESEARCH IN CHINESE MEDICINE (UNIVERSITY OF MACAU) |
Corresponding Author | Yao, D.-X.; Tang, Z.; Li, H.-F. |
Affiliation | 1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau SAR 999078, China 2.Department of Materials Science and Engineering, Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG), Southern University of Science and Technology, No. 1088, Xueyuan Rd., Shenzhen 518055, Guangdong, China 3.State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275, China 4.Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA 5.Jülich Centre for Neutron Science JCNS-2 and Peter Grünberg Institut PGI, JARA-FIT, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany 6.State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences (ICMS), University of Macau, Avenida da Universidade, Taipa, Macau SAR 999078, China |
First Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Corresponding Author Affilication | INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING |
Recommended Citation GB/T 7714 | Zhu, Y. H.,Wu, S.,Tu, B.,et al. High-temperature magnetism and crystallography of a YCrO3 single crystal[J]. Physical Review B, 2020, 101(1), 014114. |
APA | Zhu, Y. H.., Wu, S.., Tu, B.., Jin, S. J.., Huq, A.., Persson, J.., Gao, H. S.., Ouyang, D.., He, Z. B.., Yao, D.-X.., Tang, Z.., & Li, H.-F. (2020). High-temperature magnetism and crystallography of a YCrO3 single crystal. Physical Review B, 101(1), 014114. |
MLA | Zhu, Y. H.,et al."High-temperature magnetism and crystallography of a YCrO3 single crystal".Physical Review B 101.1(2020):014114. |
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