UM  > INSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Residential Collegefalse
Status已發表Published
High-temperature magnetism and crystallography of a YCrO3 single crystal
Zhu, Y. H.1; Wu, S.1; Tu, B.1,2; Jin, S. J.3; Huq, A.4; Persson, J.5; Gao, H. S.1,6; Ouyang, D.6; He, Z. B.2; Yao, D.-X.3; Tang, Z.1; Li, H.-F.1
2020-01-30
Source PublicationPhysical Review B
ISSN2469-9969
Volume101Issue:1Pages:014114
Abstract

Magnetization measurements and time-of-flight neutron powder-diffraction studies on the high-temperature (300--980 K) magnetism and crystal structure (321--1200 K) of a pulverized YCrO$_3$ single crystal have been performed. Temperature-dependent inverse magnetic susceptibility coincides with a piecewise linear function with five regimes, with which we fit a Curie-Weiss law and calculate the frustration factor $f$. The fit results indicate a formation of magnetic polarons between 300 and 540 K and a very strong magnetic frustration. By including one factor $\eta$ that represents the degree of spin interactions into the Brillouin function, we can fit well the applied-magnetic-field dependence of magnetization. No structural phase transition was observed from 321 to 1200 K. The average thermal expansions of lattice configurations (\emph{a}, \emph{b}, \emph{c}, and \emph{V}) obey well the Gr$\ddot{\texttt{u}}$neisen approximations with an anomaly appearing around 900 K, implying an isosymmetric structural phase transition, and display an anisotropic character along the crystallographic \emph{a}, \emph{b}, and \emph{c} axes with the incompressibility $K^a_0 > K^c_0 > K^b_0$. It is interesting to find that at 321 K, the local distortion size $\Delta$(O2) $\approx$ 1.96$\Delta$(O1) $\approx$ 4.32$\Delta$(Y) $\approx$ 293.89$\Delta$(Cr). Based on the refined Y-O and Cr-O bond lengths, we deduce the local distortion environments and modes of Y, Cr, O1, and O2 ions. Especially, the Y and O2 ions display obvious atomic displacement and charge subduction, which may shed light on the dielectric property of the YCrO$_3$ compound. Additionally, by comparing Kramers Mn$^{3+}$ with non-Kramers Cr$^{3+}$ ions, it is noted that being a Kramers or non-Kramers ion can strongly affect the local distortion size, whereas, it may not be able to change the detailed distortion mode.

DOI10.1103/PhysRevB.101.014114
URLView the original
Indexed BySCIE
Language英語English
WOS Research AreaMaterials Science ; Physics
WOS SubjectMaterials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000510144400001
The Source to ArticlePB_Publication
Scopus ID2-s2.0-85079555041
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Institute of Chinese Medical Sciences
THE STATE KEY LABORATORY OF QUALITY RESEARCH IN CHINESE MEDICINE (UNIVERSITY OF MACAU)
Corresponding AuthorYao, D.-X.; Tang, Z.; Li, H.-F.
Affiliation1.Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau SAR 999078, China
2.Department of Materials Science and Engineering, Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG), Southern University of Science and Technology, No. 1088, Xueyuan Rd., Shenzhen 518055, Guangdong, China
3.State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275, China
4.Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
5.Jülich Centre for Neutron Science JCNS-2 and Peter Grünberg Institut PGI, JARA-FIT, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany
6.State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences (ICMS), University of Macau, Avenida da Universidade, Taipa, Macau SAR 999078, China
First Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Corresponding Author AffilicationINSTITUTE OF APPLIED PHYSICS AND MATERIALS ENGINEERING
Recommended Citation
GB/T 7714
Zhu, Y. H.,Wu, S.,Tu, B.,et al. High-temperature magnetism and crystallography of a YCrO3 single crystal[J]. Physical Review B, 2020, 101(1), 014114.
APA Zhu, Y. H.., Wu, S.., Tu, B.., Jin, S. J.., Huq, A.., Persson, J.., Gao, H. S.., Ouyang, D.., He, Z. B.., Yao, D.-X.., Tang, Z.., & Li, H.-F. (2020). High-temperature magnetism and crystallography of a YCrO3 single crystal. Physical Review B, 101(1), 014114.
MLA Zhu, Y. H.,et al."High-temperature magnetism and crystallography of a YCrO3 single crystal".Physical Review B 101.1(2020):014114.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhu, Y. H.]'s Articles
[Wu, S.]'s Articles
[Tu, B.]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhu, Y. H.]'s Articles
[Wu, S.]'s Articles
[Tu, B.]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhu, Y. H.]'s Articles
[Wu, S.]'s Articles
[Tu, B.]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.