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Super-Necking Crystal Growth and Structural and Magnetic Properties of SrTb$_2$O$_4$ Single Crystals
Wu, S.; Zhu, Y.; Gao, H.; Xiao, Y.; Xia, J.; Zhou, P.; Ouyang, D.; Li, Z.; Chen, Z.; Tang, Z.; Li, H.-F.
2020-06-29
Source PublicationACS Omega
ISSN2470-1343
Pages16584-16594
Abstract

We report on single-crystal growths of the SrTb$_2$O$_4$ compound by a super-necking technique with a laser-floating-zone furnace and study the stoichiometry, growth mode, and structural and magnetic properties by scanning electronic microscopy, neutron Laue, X-ray powder diffraction, and the physical property measurement system. We optimized the growth parameters, mainly the growth speed, atmosphere, and the addition of a Tb$_4$O$_7$ raw material. Neutron Laue diffraction displays the characteristic feature of a single crystal. Our study reveals an atomic ratio of Sr{:}Tb $ = 0.97(2){:}2.00(1)$ and a possible layer by layer crystal growth mode. Our X-ray powder diffraction study determines the crystal structure, lattice constants and atomic positions. The paramagnetic (PM) Curie{--}Weiss (CW) temperature $\theta_{\texttt{CW}} =$ 5.00(4) K, and the effective PM moment $M^{\texttt{eff}}_{\texttt{mea}} =$ 10.97(1) $\mu_\texttt{B}$ per Tb$^{3+}$ ion. The data of magnetization versus temperature can be divided into three regimes, showing a coexistence of antiferromagnetic and ferromagnetic interactions. This probably leads to the magnetic frustration in the SrTb$_2$O$_4$ compound. The magnetization at 2 K and 14 T originates from both the Tb1 and Tb2 sites and is strongly frustrated with an expected saturation field at $\sim$41.5 T, displaying an intricate phase diagram with three ranges.

KeywordCrystal Growth Structural And Magnetic Properties srtb$_2$o$_4$ Single Crystals
DOI10.1021/acsomega.0c01360
URLView the original
Language英語English
WOS IDWOS:000562142500030
The Source to ArticlePB_Publication
Scopus ID2-s2.0-85089293212
Fulltext Access
Citation statistics
Document TypeJournal article
CollectionUniversity of Macau
Corresponding AuthorChen, Z.; Tang, Z.; Li, H.-F.
Recommended Citation
GB/T 7714
Wu, S.,Zhu, Y.,Gao, H.,et al. Super-Necking Crystal Growth and Structural and Magnetic Properties of SrTb$_2$O$_4$ Single Crystals[J]. ACS Omega, 2020, 16584-16594.
APA Wu, S.., Zhu, Y.., Gao, H.., Xiao, Y.., Xia, J.., Zhou, P.., Ouyang, D.., Li, Z.., Chen, Z.., Tang, Z.., & Li, H.-F. (2020). Super-Necking Crystal Growth and Structural and Magnetic Properties of SrTb$_2$O$_4$ Single Crystals. ACS Omega, 16584-16594.
MLA Wu, S.,et al."Super-Necking Crystal Growth and Structural and Magnetic Properties of SrTb$_2$O$_4$ Single Crystals".ACS Omega (2020):16584-16594.
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