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Uncoordinated inorganic salt in 1D chain structure: formation of a novel supermolecule [HgBr2(ptz)]2 · HgBr2
Xuanjun Zhang1; Wentao Yu2; Yi Xie1; Qingrui Zhao1; Yupeng Tian3
2003
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
Volume6Issue:10Pages:1338-1340
Abstract

A novel supermolecule [HgBr2(ptz)](2) (.) HgBr2 (ptz = phenothiazine) with uncoordinated inorganicsalt HgBr2 presented in a 1D chain was prepared. The bulky ligand phenothiazine has unusual coordination mode with large steric inhibition perpendicular to the chain direction. The uncoordinated HgBr2 molecule was stabilized by multiple weak HgBr2 interactions and the whole structure was also stabilized by strong pi-pi interactions and N-(HBr)-Br-... hydrogen bonds to form 2D network. (C) 2003 Elsevier B.V. All rights reserved.

KeywordSupermolecule Photoluminescence 1d Chain Coordination Mode
DOI10.1016/j.inoche.2003.08.013
Indexed BySCIE
Language英語English
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000185821600016
Scopus ID2-s2.0-0141995019
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Document TypeJournal article
CollectionFaculty of Health Sciences
Affiliation1.Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China
2.The State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, PR China
3.Department of Chemistry, Anhui University, Hefei 230039, PR China
Recommended Citation
GB/T 7714
Xuanjun Zhang,Wentao Yu,Yi Xie,et al. Uncoordinated inorganic salt in 1D chain structure: formation of a novel supermolecule [HgBr2(ptz)]2 · HgBr2[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6(10), 1338-1340.
APA Xuanjun Zhang., Wentao Yu., Yi Xie., Qingrui Zhao., & Yupeng Tian (2003). Uncoordinated inorganic salt in 1D chain structure: formation of a novel supermolecule [HgBr2(ptz)]2 · HgBr2. INORGANIC CHEMISTRY COMMUNICATIONS, 6(10), 1338-1340.
MLA Xuanjun Zhang,et al."Uncoordinated inorganic salt in 1D chain structure: formation of a novel supermolecule [HgBr2(ptz)]2 · HgBr2".INORGANIC CHEMISTRY COMMUNICATIONS 6.10(2003):1338-1340.
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